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- W3136276513 abstract "To understand the responses of self-assembly in mixtures containing zwitterionic amphiphilic chains to high pressure, we introduce a self-consistent field theory in combination with a molecular equation-of-state model for them in a primitive way. The free energy density for those in the bulk state is first formulated. Its locally equilibrated excess part is then incorporated into Edwards Hamiltonian along with the electrostatic energy contributions to elicit the saddle point approximation to the partition function with proper self-consistent field equations. It is shown that charge–charge correlations enhance self-assembling tendency for the amphiphiles with the opposite charges on one component side, as the medium dielectric constant εr decreases. Those with the opposite charges at the two chain ends respond in a more complicated way to εr. Densification by applied pressure strengthens the self-assembly for both at a moderate εr, similar to typical phospholipids, but pressure effects are strongly dependent on the position of charges along the chains at a lower εr. It is argued that the manipulation of the dielectric environment and disparity in component dispersion interactions can yield useful materials exhibiting various types of baroresponsivity or thermoresponsivity with re-entrant self-assembly." @default.
- W3136276513 created "2021-03-29" @default.
- W3136276513 creator A5018422973 @default.
- W3136276513 creator A5039403211 @default.
- W3136276513 creator A5079971678 @default.
- W3136276513 date "2021-03-23" @default.
- W3136276513 modified "2023-09-23" @default.
- W3136276513 title "Pressure Effects on Self-Assembly in Mixtures Containing Zwitterionic Amphiphiles" @default.
- W3136276513 cites W1490178827 @default.
- W3136276513 cites W1513032216 @default.
- W3136276513 cites W1601171111 @default.
- W3136276513 cites W179543256 @default.
- W3136276513 cites W1966030549 @default.
- W3136276513 cites W1968532116 @default.
- W3136276513 cites W1968847015 @default.
- W3136276513 cites W1969837995 @default.
- W3136276513 cites W1970495824 @default.
- W3136276513 cites W1971106383 @default.
- W3136276513 cites W1971990401 @default.
- W3136276513 cites W1973912315 @default.
- W3136276513 cites W1975899172 @default.
- W3136276513 cites W1976915573 @default.
- W3136276513 cites W1979364630 @default.
- W3136276513 cites W1979685861 @default.
- W3136276513 cites W1983866015 @default.
- W3136276513 cites W1987311480 @default.
- W3136276513 cites W1988889191 @default.
- W3136276513 cites W1989803297 @default.
- W3136276513 cites W1990781452 @default.
- W3136276513 cites W1996013733 @default.
- W3136276513 cites W2000769681 @default.
- W3136276513 cites W2005414622 @default.
- W3136276513 cites W2006435770 @default.
- W3136276513 cites W2009068183 @default.
- W3136276513 cites W2018842022 @default.
- W3136276513 cites W2022283214 @default.
- W3136276513 cites W2028602090 @default.
- W3136276513 cites W2034309889 @default.
- W3136276513 cites W2035968908 @default.
- W3136276513 cites W2037129162 @default.
- W3136276513 cites W2037929372 @default.
- W3136276513 cites W2040066871 @default.
- W3136276513 cites W2041862937 @default.
- W3136276513 cites W2042102793 @default.
- W3136276513 cites W2044931685 @default.
- W3136276513 cites W2046106665 @default.
- W3136276513 cites W2046789301 @default.
- W3136276513 cites W2048979035 @default.
- W3136276513 cites W2057282933 @default.
- W3136276513 cites W2057986494 @default.
- W3136276513 cites W2062211668 @default.
- W3136276513 cites W2062468679 @default.
- W3136276513 cites W2064202374 @default.
- W3136276513 cites W2066195845 @default.
- W3136276513 cites W2067153323 @default.
- W3136276513 cites W2070840453 @default.
- W3136276513 cites W2073446979 @default.
- W3136276513 cites W2073503574 @default.
- W3136276513 cites W2077293962 @default.
- W3136276513 cites W2078041358 @default.
- W3136276513 cites W2079059951 @default.
- W3136276513 cites W2086315468 @default.
- W3136276513 cites W2086829114 @default.
- W3136276513 cites W2089406268 @default.
- W3136276513 cites W2092729193 @default.
- W3136276513 cites W2093107148 @default.
- W3136276513 cites W2095197640 @default.
- W3136276513 cites W2106226353 @default.
- W3136276513 cites W2108944652 @default.
- W3136276513 cites W2112597123 @default.
- W3136276513 cites W2113404900 @default.
- W3136276513 cites W2127963392 @default.
- W3136276513 cites W2164513199 @default.
- W3136276513 cites W2172949807 @default.
- W3136276513 cites W2216819823 @default.
- W3136276513 cites W2302551836 @default.
- W3136276513 cites W2313726239 @default.
- W3136276513 cites W2316934604 @default.
- W3136276513 cites W2327021188 @default.
- W3136276513 cites W2329330520 @default.
- W3136276513 cites W2332543856 @default.
- W3136276513 cites W2335096306 @default.
- W3136276513 cites W2343295012 @default.
- W3136276513 cites W2400556273 @default.
- W3136276513 cites W2416638092 @default.
- W3136276513 cites W2526054337 @default.
- W3136276513 cites W2562137968 @default.
- W3136276513 cites W2566370770 @default.
- W3136276513 cites W260422282 @default.
- W3136276513 cites W2772283214 @default.
- W3136276513 cites W2852595232 @default.
- W3136276513 cites W2884472513 @default.
- W3136276513 cites W2904046471 @default.
- W3136276513 cites W2954453835 @default.
- W3136276513 cites W2995620713 @default.
- W3136276513 doi "https://doi.org/10.1021/acs.langmuir.1c00024" @default.
- W3136276513 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33754727" @default.
- W3136276513 hasPublicationYear "2021" @default.