Matches in SemOpenAlex for { <https://semopenalex.org/work/W3136334825> ?p ?o ?g. }
- W3136334825 endingPage "3357" @default.
- W3136334825 startingPage "3347" @default.
- W3136334825 abstract "Self-nucleation (SN) and strong shear methods were employed to obtain less-entangled melts in poly(ε-caprolactone) and its blends with poly(styrene-co-acrylonitrile). The effect of shear flow on the isothermal and nonisothermal crystallization behavior of the less-entangled melts was studied by rheology and shear-Raman spectroscopy. Weak shear with a Rouse Weissenberg number WiR < 1 causes a lower crystallization temperature (Tc) and a longer half-crystallization time (t1/2) for both SN and strongly sheared melts under nonisothermal and isothermal conditions, respectively. This indicates that the crystallization of the less-entangled melts is decelerated by weak shear, implying that the melt memory effect from the crystallization is weakened. This phenomenon is ascribed to the accelerated chain re-entanglement under a weak shear flow, as verified by the rheological responses under the interrupted shear flow, stress relaxation, and oscillatory time sweep. It is believed that shear flow increases the free energy of polymer chains, which overcomes the free energy barriers for re-entanglement, activates the reptation, and speeds up the chain re-entanglements." @default.
- W3136334825 created "2021-03-29" @default.
- W3136334825 creator A5056448190 @default.
- W3136334825 creator A5064684366 @default.
- W3136334825 date "2021-03-24" @default.
- W3136334825 modified "2023-10-14" @default.
- W3136334825 title "Weak Shear-Induced Slowdown in Crystallization of Less-Entangled Poly(ε-caprolactone)" @default.
- W3136334825 cites W1198588957 @default.
- W3136334825 cites W1976031861 @default.
- W3136334825 cites W1978474708 @default.
- W3136334825 cites W1979699468 @default.
- W3136334825 cites W1986386802 @default.
- W3136334825 cites W1988440544 @default.
- W3136334825 cites W1995839340 @default.
- W3136334825 cites W1996293282 @default.
- W3136334825 cites W2012539447 @default.
- W3136334825 cites W2012670796 @default.
- W3136334825 cites W2013712870 @default.
- W3136334825 cites W2016286640 @default.
- W3136334825 cites W2019927397 @default.
- W3136334825 cites W2022414440 @default.
- W3136334825 cites W2036248814 @default.
- W3136334825 cites W2037878111 @default.
- W3136334825 cites W2051300354 @default.
- W3136334825 cites W2060369688 @default.
- W3136334825 cites W2063673560 @default.
- W3136334825 cites W2068785709 @default.
- W3136334825 cites W2069860202 @default.
- W3136334825 cites W2073774194 @default.
- W3136334825 cites W2073822864 @default.
- W3136334825 cites W2074366690 @default.
- W3136334825 cites W2082096824 @default.
- W3136334825 cites W2084946274 @default.
- W3136334825 cites W2090632605 @default.
- W3136334825 cites W2104186198 @default.
- W3136334825 cites W2109926164 @default.
- W3136334825 cites W2129317889 @default.
- W3136334825 cites W2134030032 @default.
- W3136334825 cites W2139053036 @default.
- W3136334825 cites W2140630733 @default.
- W3136334825 cites W2141885477 @default.
- W3136334825 cites W2146996718 @default.
- W3136334825 cites W2242341198 @default.
- W3136334825 cites W2283609558 @default.
- W3136334825 cites W2302475536 @default.
- W3136334825 cites W2322250178 @default.
- W3136334825 cites W2322707590 @default.
- W3136334825 cites W2323955534 @default.
- W3136334825 cites W2332391986 @default.
- W3136334825 cites W2417745103 @default.
- W3136334825 cites W2474823820 @default.
- W3136334825 cites W2493119040 @default.
- W3136334825 cites W2507600465 @default.
- W3136334825 cites W2521800770 @default.
- W3136334825 cites W2528288718 @default.
- W3136334825 cites W2569082314 @default.
- W3136334825 cites W2588189319 @default.
- W3136334825 cites W2604999809 @default.
- W3136334825 cites W2772483065 @default.
- W3136334825 cites W2783764813 @default.
- W3136334825 cites W2788848816 @default.
- W3136334825 cites W2791711925 @default.
- W3136334825 cites W2793372226 @default.
- W3136334825 cites W2801245129 @default.
- W3136334825 cites W2807608631 @default.
- W3136334825 cites W2807633362 @default.
- W3136334825 cites W2901224449 @default.
- W3136334825 cites W2901737428 @default.
- W3136334825 cites W2913433427 @default.
- W3136334825 cites W2921539655 @default.
- W3136334825 cites W2988367394 @default.
- W3136334825 cites W3084982992 @default.
- W3136334825 doi "https://doi.org/10.1021/acs.macromol.1c00204" @default.
- W3136334825 hasPublicationYear "2021" @default.
- W3136334825 type Work @default.
- W3136334825 sameAs 3136334825 @default.
- W3136334825 citedByCount "10" @default.
- W3136334825 countsByYear W31363348252021 @default.
- W3136334825 countsByYear W31363348252022 @default.
- W3136334825 countsByYear W31363348252023 @default.
- W3136334825 crossrefType "journal-article" @default.
- W3136334825 hasAuthorship W3136334825A5056448190 @default.
- W3136334825 hasAuthorship W3136334825A5064684366 @default.
- W3136334825 hasConcept C121332964 @default.
- W3136334825 hasConcept C133347239 @default.
- W3136334825 hasConcept C135768490 @default.
- W3136334825 hasConcept C159985019 @default.
- W3136334825 hasConcept C165682214 @default.
- W3136334825 hasConcept C188027245 @default.
- W3136334825 hasConcept C192562407 @default.
- W3136334825 hasConcept C200990466 @default.
- W3136334825 hasConcept C203036418 @default.
- W3136334825 hasConcept C2779680939 @default.
- W3136334825 hasConcept C521977710 @default.
- W3136334825 hasConcept C61048295 @default.
- W3136334825 hasConcept C94786355 @default.
- W3136334825 hasConcept C96035792 @default.
- W3136334825 hasConcept C97355855 @default.