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- W3136383895 abstract "Abstract Molybdenum oxycarbide clusters are novel nanomaterials that exhibit attractive catalytic activity; however, the methods for their production are currently very restrictive. This work represents a new strategy for the creation of near‐subnanometer size molybdenum oxycarbide clusters on multilayer graphene. To adsorb Mo‐based polyoxometalates of the type [PMo 12 O 40 ] 3− as a precursor for Mo oxycarbide clusters, the novel tripodal‐phenyl cation N , N , N ‐tri(4‐phenylbutyl)‐ N ‐methylammonium ([TPBMA] + ) is synthesized. [TPBMA] + exhibits superior adsorption on multilayer graphene compared to commercially available cations such as tetrabutylammonium ([ n Bu 4 N] + ) and tetraphenylphosphonium ([PPh 4 ] + ). Using [TPBMA] + as an anchor, highly dispersed precursor clusters (diameter: 1.0 ± 0.2 nm) supported on multilayer graphene are obtained, as confirmed by high‐resolution scanning transmission electron microscopy. Remarkably, this new material achieves the catalytic reduction of CO 2 to selectively produce CO (≈99.9%) via the reverse water‐gas‐shift reaction, by applying carbothermal hydrogen reduction to generate Mo oxycarbide clusters in situ." @default.
- W3136383895 created "2021-03-29" @default.
- W3136383895 creator A5036341706 @default.
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- W3136383895 date "2021-03-24" @default.
- W3136383895 modified "2023-10-06" @default.
- W3136383895 title "Highly Dispersed Molybdenum Oxycarbide Clusters Supported on Multilayer Graphene for the Selective Reduction of Carbon Dioxide" @default.
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- W3136383895 doi "https://doi.org/10.1002/smll.202008127" @default.
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