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- W3136421589 abstract "2-Alkyl cycloketones are essential chemicals and intermediates for synthetic perfumes and pesticides, which are conventionally produced by multistep process including aldol condensation, separation and hydrogenation. In present work, a batch one-pot cascade approach using aldehydes and cycloketones as the raw materials, and a bifunctional Pd/ZrO2 catalyst was developed for the synthesis of 2-alkyl cycloketones, e.g., cyclohexanone and cycloheptanone. Very high aldehydes (except for paraldehyde with large steric hindrance) conversion and high yields for 2-alkyl cycloketones (e.g., 99 % of conversion for n-butanal and 76 wt.% of yield for 2-butyl cyclohexanone) were obtained at mild temperature of 140 °C. After 10 cycles of reuse, Pd/ZrO2 catalyst showed slight deactivation (ca. 5 % conversion and 10 % yield losses), due to the coke on the catalyst. However, the performance of the catalyst was completely recovered after an oxidative regeneration." @default.
- W3136421589 created "2021-03-29" @default.
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- W3136421589 date "2021-04-01" @default.
- W3136421589 modified "2023-09-23" @default.
- W3136421589 title "One-pot synthesis of 2-alkyl cycloketones on bifunctional Pd/ZrO2 catalyst" @default.
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- W3136421589 doi "https://doi.org/10.1016/j.apcata.2021.118107" @default.
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