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- W3136434397 abstract "In this work, platinum(0) nanoparticles are deposited on the surface of magnetic cobalt ferrite forming magnetically separable Pt0/CoFe2O4 nanoparticles, which are efficient catalysts in H2 generation from the hydrolysis of ammonia borane. Catalytic activity of Pt0/CoFe2O4 nanoparticles decreases with the increasing platinum loading, parallel to the average particle size. Pt0/CoFe2O4 (0.23% wt. Pt) nanoparticles have an average diameter of 2.30 ± 0.47 nm and show an extraordinary turnover frequency of 3628 min−1 in releasing 3.0 equivalent H2 per mole of ammonia borane from the hydrolysis at 25.0 °C. Moreover, the magnetically separable Pt0/CoFe2O4 nanoparticles possess high reusability retaining 100% of their initial catalytic activity even after ten runs of hydrolysis. The superb catalytic activity and outstanding reusability make the Pt0/CoFe2O4 nanoparticles very attractive catalysts for the hydrogen generation systems in portable and stationary fuel cell applications." @default.
- W3136434397 created "2021-03-29" @default.
- W3136434397 creator A5020532334 @default.
- W3136434397 creator A5039448841 @default.
- W3136434397 date "2021-08-01" @default.
- W3136434397 modified "2023-10-14" @default.
- W3136434397 title "Cobalt ferrite supported platinum nanoparticles: Superb catalytic activity and outstanding reusability in hydrogen generation from the hydrolysis of ammonia borane" @default.
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- W3136434397 doi "https://doi.org/10.1016/j.jcis.2021.03.039" @default.
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