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• W3136494920 abstract "Abstract In this work, the relationship among the thermal history, refractive index (RI), and structures of Yb 3+ /Al 3+ /P 5+ /F − ‐co‐doped silica glass is studied. We reveal the structural origin of the thermally induced RI change in the Heraeus F300 and Yb 3+ /Al 3+ /P 5+ /F − ‐co‐doped silica glasses with different states of thermal history by advanced solid‐state nuclear magnetic resonance and Raman scattering techniques, and the effect of the thermal history on the beam quality of Yb 3+ ‐doped large‐mode‐area photonic crystal fiber (LMA PCF). The structural analysis demonstrates that the RI change in the glass is inextricably linked to the change in the AlPO 4 domains, coordination number of the Al and Si–O–Si rings. An intimate and direct connection of the thermally induced physical behaviors is developed with the structural pictures of glasses, and the beam quality of the LMA PCF is greatly improved by proper thermal annealing. The results provide a significant reference for the precise manipulation of the numerical aperture of Yb 3+ ‐doped active fiber." @default.
• W3136494920 created "2021-03-29" @default.
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• W3136494920 date "2021-03-31" @default.
• W3136494920 modified "2023-10-15" @default.
• W3136494920 title "Structural origin of thermally induced refractive index changes in Yb ³⁺ /Al ³⁺ /P ⁵⁺ /F ⁻ ‐co‐doped silica glass" @default.
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• W3136494920 doi "https://doi.org/10.1111/jace.17777" @default.
• W3136494920 hasPublicationYear "2021" @default.
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