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- W3136572333 abstract "A selective aerobic oxidative cleavage of CC bond is developed with black nickel oxide (NiOx) as the catalyst. For the oxidation of 1-phenyl-1, 2-ethanediol, a 97.5% conversion in 96.7% selectivity of benzaldehyde is obtained under 0.3 MPa of O2 at 140 °C for 3 h. The relationship between the catalytic performance of NiOx and structure is discussed. It is concluded that the existence of Ni3+ should be crucial to the activity of catalyst. Moreover, the recycling experiments showed that the catalyst can retain a high activity even after being reused for five times." @default.
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- W3136572333 date "2021-06-01" @default.
- W3136572333 modified "2023-09-30" @default.
- W3136572333 title "A novel selective oxidative cleavage of C C bond mediated by black nickel oxide in the presence of molecular oxygen" @default.
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- W3136572333 doi "https://doi.org/10.1016/j.catcom.2021.106305" @default.
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