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- W3136611432 abstract "Chlorine dioxide (ClO2) is used in water treatment for disinfection, pre-oxidation, and recently pollutant degradation. However, there are significant gaps in the knowledge of byproduct formation in ClO2 applications. The mechanisms by which organic compounds react with ClO2 differ vastly with the slightest change in the reaction centre and its adjacent reactive moieties (e.g. phenol, hydroquinone, vanillin). This leads to the formation of various inorganic byproducts such as chlorite, chloride, and free chlorine as a secondary oxidant. Chlorite and chlorate are regulated, and free chlorine can further contribute to the formation of halogenated byproducts. The current chapter provides an overview of the current knowledge for the mechanisms of ClO2 oxidation and byproduct formation. The reactive moieties of organic compounds towards ClO2 will be discussed, and a compilation of their reaction rates will be presented. Moreover, the pathways that might form free chlorine and the benefit of its formation to the degradation of recalcitrant pollutants towards ClO2 are discussed. This chapter also covers how inorganic byproduct formation will differ based on the reaction partner and how they interact with each other. In the end, measures of byproducts reduction involving ClO2 will be discussed." @default.
- W3136611432 created "2021-03-29" @default.
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- W3136611432 date "2021-01-01" @default.
- W3136611432 modified "2023-10-03" @default.
- W3136611432 title "Mechanisms and byproduct formation in the application of chlorine dioxide" @default.
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- W3136611432 doi "https://doi.org/10.1016/bs.coac.2021.01.003" @default.
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