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• W3136644465 startingPage "3210" @default.
• W3136644465 abstract "α-MoO3 is a promising electrode material for electrocapacitive energy storage. However, it has poor stability in aqueous electrolytes due to dissolution in water. Here, we demonstrate that an α-MoO3 electrode prepared using the electrochemical deposition method is stable over a wide potential window of 2.2 V in a neutral aqueous electrolyte. The improved stability of the α-MoO3 electrode in water is attributable to enhanced electron conductivity, which minimizes the polarization-induced structural collapse, and the dense microstructure of the α-MoO3 film electrode. The widened potential window is related to the electrocatalytic inactivity of the α-MoO3 toward water electrolysis and the high overpotentials of the neutral electrolyte toward H2 and O2 evolution reactions. A symmetric supercapacitor cell fabricated with the electrochemically deposited α-MoO3 electrode delivers a specific energy as high as ∼22 Wh/kg at a specific power of ∼301 W/kg. This work demonstrates that the electrochemical deposition method is a viable approach to fabricating α-MoO3 electrodes for aqueous electrochemical energy storage." @default.
• W3136644465 created "2021-03-29" @default.
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• W3136644465 date "2021-03-24" @default.
• W3136644465 modified "2023-10-12" @default.
• W3136644465 title "Stable α-MoO₃ Electrode with a Widened Electrochemical Potential Window for Aqueous Electrochemical Capacitors" @default.
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• W3136644465 doi "https://doi.org/10.1021/acsaem.0c02990" @default.
• W3136644465 hasPublicationYear "2021" @default.
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