Matches in SemOpenAlex for { <https://semopenalex.org/work/W3136709555> ?p ?o ?g. }
- W3136709555 endingPage "2100072" @default.
- W3136709555 startingPage "2100072" @default.
- W3136709555 abstract "A semi-crystalline, shape memory polymer (SMP) is fabricated by free radical cross-linking, polymerization, and grafting in a blend of n-octadecyl acrylate and polybutadiene (PB). Poly(n-octadecyl acrylate) (PODA) is a side-chain crystalline polymer, which serves as the structure-fixing network counterbalancing the elastically deformed, cross-linked polymer network. At a constant 50/50 ratio of monomer and polymer the amount of free radical initiator, dicumyl peroxide (DCP) is varied from 1% to 5% w/w PB. From swelling measurements and calculation of the cross-link density it is determined that DCP produces greater than one cross-link per DCP molecule. It is found that lower cross-linking efficiency is favorable for higher shape fixity. This lower efficiency is found to produce a higher degree of crystallinity of the PODA in the 2–5% DCP samples, which is determined to be the main driver of higher shape fixity of the polymer. A SMP with >90% fixity and 100% recovery at uniaxial strains from 34–79% is achieved. This material should be useful for mold processing of shape memory articles. This approach provides a method to decouple the elastomeric and thermoplastic portions of a SMP to convert commodity elastomers into SMPs and tailor the shape memory response." @default.
- W3136709555 created "2021-03-29" @default.
- W3136709555 creator A5000142008 @default.
- W3136709555 creator A5001502589 @default.
- W3136709555 creator A5022663760 @default.
- W3136709555 creator A5025885077 @default.
- W3136709555 creator A5029559654 @default.
- W3136709555 date "2021-03-24" @default.
- W3136709555 modified "2023-09-27" @default.
- W3136709555 title "Cross‐linked Poly(Octadecyl Acrylate)/Polybutadiene Shape Memory Polymer Blends Prepared by Simultaneous Free Radical Cross‐linking, Grafting and Polymerization of Octadecyl Acrylate/Polybutadiene Blends" @default.
- W3136709555 cites W1970281886 @default.
- W3136709555 cites W1972675654 @default.
- W3136709555 cites W1975508278 @default.
- W3136709555 cites W1979485117 @default.
- W3136709555 cites W1979754244 @default.
- W3136709555 cites W1988538155 @default.
- W3136709555 cites W1988638865 @default.
- W3136709555 cites W1991614010 @default.
- W3136709555 cites W2000269196 @default.
- W3136709555 cites W2002899682 @default.
- W3136709555 cites W2004275847 @default.
- W3136709555 cites W2005690595 @default.
- W3136709555 cites W2011733070 @default.
- W3136709555 cites W2013880912 @default.
- W3136709555 cites W2016421336 @default.
- W3136709555 cites W2020598517 @default.
- W3136709555 cites W2021158547 @default.
- W3136709555 cites W2022300369 @default.
- W3136709555 cites W2027209499 @default.
- W3136709555 cites W2033067649 @default.
- W3136709555 cites W2033905274 @default.
- W3136709555 cites W2043013909 @default.
- W3136709555 cites W2043025946 @default.
- W3136709555 cites W2045144084 @default.
- W3136709555 cites W2054744586 @default.
- W3136709555 cites W2055964569 @default.
- W3136709555 cites W2057314363 @default.
- W3136709555 cites W2062527694 @default.
- W3136709555 cites W2063310888 @default.
- W3136709555 cites W2092794304 @default.
- W3136709555 cites W2102636450 @default.
- W3136709555 cites W2114446270 @default.
- W3136709555 cites W2124113023 @default.
- W3136709555 cites W2125276562 @default.
- W3136709555 cites W2126046022 @default.
- W3136709555 cites W2158109938 @default.
- W3136709555 cites W2168554493 @default.
- W3136709555 cites W2276889479 @default.
- W3136709555 cites W2286543598 @default.
- W3136709555 cites W2312557411 @default.
- W3136709555 cites W2319457141 @default.
- W3136709555 cites W2320180682 @default.
- W3136709555 cites W2332324726 @default.
- W3136709555 cites W2555967066 @default.
- W3136709555 cites W2611751185 @default.
- W3136709555 cites W2768641332 @default.
- W3136709555 cites W2789881656 @default.
- W3136709555 cites W2792981251 @default.
- W3136709555 cites W2898923711 @default.
- W3136709555 cites W2911480513 @default.
- W3136709555 cites W2921622277 @default.
- W3136709555 cites W2921843702 @default.
- W3136709555 cites W2944504100 @default.
- W3136709555 cites W3189601278 @default.
- W3136709555 cites W4244569713 @default.
- W3136709555 cites W4255880045 @default.
- W3136709555 doi "https://doi.org/10.1002/marc.202100072" @default.
- W3136709555 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33759273" @default.
- W3136709555 hasPublicationYear "2021" @default.
- W3136709555 type Work @default.
- W3136709555 sameAs 3136709555 @default.
- W3136709555 citedByCount "7" @default.
- W3136709555 countsByYear W31367095552022 @default.
- W3136709555 countsByYear W31367095552023 @default.
- W3136709555 crossrefType "journal-article" @default.
- W3136709555 hasAuthorship W3136709555A5000142008 @default.
- W3136709555 hasAuthorship W3136709555A5001502589 @default.
- W3136709555 hasAuthorship W3136709555A5022663760 @default.
- W3136709555 hasAuthorship W3136709555A5025885077 @default.
- W3136709555 hasAuthorship W3136709555A5029559654 @default.
- W3136709555 hasConcept C111998727 @default.
- W3136709555 hasConcept C15920480 @default.
- W3136709555 hasConcept C159985019 @default.
- W3136709555 hasConcept C166940927 @default.
- W3136709555 hasConcept C188027245 @default.
- W3136709555 hasConcept C192562407 @default.
- W3136709555 hasConcept C2779989194 @default.
- W3136709555 hasConcept C2780901341 @default.
- W3136709555 hasConcept C38052585 @default.
- W3136709555 hasConcept C44228677 @default.
- W3136709555 hasConcept C46275449 @default.
- W3136709555 hasConcept C521977710 @default.
- W3136709555 hasConcept C92328351 @default.
- W3136709555 hasConceptScore W3136709555C111998727 @default.
- W3136709555 hasConceptScore W3136709555C15920480 @default.
- W3136709555 hasConceptScore W3136709555C159985019 @default.
- W3136709555 hasConceptScore W3136709555C166940927 @default.
- W3136709555 hasConceptScore W3136709555C188027245 @default.