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- W3136803771 abstract "Organic phase change materials (PCMs) have attracted considerable attention for thermal energy storage applications because of their non-toxicity, suitable working temperature range and excellent thermal/chemical stability. However, most traditional organic PCMs have small molecular structures and are prone to leakage during fusion. To address this problem and enhance the shape-stability of organic PCMs, nanosphere-shaped porphyrin-ferrocenyl conjugated microporous polymers (PFCMPs) with high porosity (~ 650 m2/g) were solvothermally synthesized using a Diels-Alder reaction between 1,1′-ferrocenedicarboxaldehyde and pyrrole in the presence of glacial acetic acid and anhydrous Lewis acids (FeCl3, AlCl3, and CuCl2). The PFCMPs were then encapsulated with PCMs, that is, 1-octadecanol (ODA), to prepare the composite materials of [email protected] The optimized composite exhibited a high latent heat (up to 153.8 J/g), excellent reversibility (negligible change in latent heat upon 100 cycles of heating–cooling), good shape stability, and long heat storage durability (425 s), making it a promising candidate for solar thermal energy engineering and management." @default.
- W3136803771 created "2021-03-29" @default.
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- W3136803771 date "2021-08-01" @default.
- W3136803771 modified "2023-09-30" @default.
- W3136803771 title "Solvothermal synthesis of porphyrin-ferrocenyl conjugated microporous polymer nanospheres for shape-stable phase change materials with improved latent heat and cyclability" @default.
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- W3136803771 doi "https://doi.org/10.1016/j.jcis.2021.03.111" @default.
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