Matches in SemOpenAlex for { <https://semopenalex.org/work/W3136997209> ?p ?o ?g. }
- W3136997209 abstract "The effects of the chemical environment of menaquinones (all-trans MK-4 and all-trans MK-7) incorporated in lipid monolayers on mercury electrodes have been studied with respect to the thermodynamics and kinetics of their electrochemistry. The chemical environment relates to the composition of lipid films as well as the adjacent aqueous phase. It could be shown that the addition of all-trans MK-4 to TMCL does not change the phase transition temperatures of TMCL. In case of DMPC monolayers, the presence of cholesterol has no effect on the thermodynamics (formal redox potentials) of all-trans MK-7, but the kinetics are affected. Addition of an inert electrolyte (sodium perchlorate; change of ionic strength) to the aqueous phase shifts the redox potentials of all-trans MK-7 only slightly. The formal redox potentials of all-trans MK-4 were determined in TMCL and nCL monolayers and found to be higher in nCL monolayers than in TMCL monolayers. The apparent electron transfer rate constants, transfer coefficients and activation energies of all-trans MK-4 in cardiolipins have been also determined. Most surprisingly, the apparent electron transfer rate constants of all-trans MK-4 exhibit an opposite pH dependence for TMCL and nCL films: the rate constants increase in TMCL films with increasing pH, but in nCL films they increase with decreasing pH. This study is a contribution to understand environmental effects on the redox properties of membrane bond redox systems." @default.
- W3136997209 created "2021-03-29" @default.
- W3136997209 creator A5004602032 @default.
- W3136997209 creator A5006747745 @default.
- W3136997209 creator A5012677128 @default.
- W3136997209 creator A5038194068 @default.
- W3136997209 creator A5057775904 @default.
- W3136997209 creator A5060974081 @default.
- W3136997209 creator A5076334542 @default.
- W3136997209 date "2021-03-17" @default.
- W3136997209 modified "2023-09-26" @default.
- W3136997209 title "The effects of the chemical environment of menaquinones in lipid monolayers on mercury electrodes on the thermodynamics and kinetics of their electrochemistry" @default.
- W3136997209 cites W1497754562 @default.
- W3136997209 cites W175784754 @default.
- W3136997209 cites W1972122807 @default.
- W3136997209 cites W1975143041 @default.
- W3136997209 cites W1985868705 @default.
- W3136997209 cites W1995471730 @default.
- W3136997209 cites W2003677679 @default.
- W3136997209 cites W2006636051 @default.
- W3136997209 cites W2016800420 @default.
- W3136997209 cites W2017074521 @default.
- W3136997209 cites W2041022595 @default.
- W3136997209 cites W2043688876 @default.
- W3136997209 cites W2064546283 @default.
- W3136997209 cites W2066299208 @default.
- W3136997209 cites W2069500178 @default.
- W3136997209 cites W2074166779 @default.
- W3136997209 cites W2084991190 @default.
- W3136997209 cites W2085371119 @default.
- W3136997209 cites W2095352115 @default.
- W3136997209 cites W2119870811 @default.
- W3136997209 cites W2142083551 @default.
- W3136997209 cites W2267211839 @default.
- W3136997209 cites W2296542935 @default.
- W3136997209 cites W2322069423 @default.
- W3136997209 cites W2489958357 @default.
- W3136997209 cites W2725326453 @default.
- W3136997209 cites W2790295811 @default.
- W3136997209 cites W2914302308 @default.
- W3136997209 cites W2928483119 @default.
- W3136997209 cites W3004264911 @default.
- W3136997209 cites W3009339608 @default.
- W3136997209 cites W3014826793 @default.
- W3136997209 cites W3023015509 @default.
- W3136997209 cites W4243346947 @default.
- W3136997209 cites W1584635981 @default.
- W3136997209 doi "https://doi.org/10.1007/s00249-021-01512-w" @default.
- W3136997209 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8260536" @default.
- W3136997209 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33730176" @default.
- W3136997209 hasPublicationYear "2021" @default.
- W3136997209 type Work @default.
- W3136997209 sameAs 3136997209 @default.
- W3136997209 citedByCount "0" @default.
- W3136997209 crossrefType "journal-article" @default.
- W3136997209 hasAuthorship W3136997209A5004602032 @default.
- W3136997209 hasAuthorship W3136997209A5006747745 @default.
- W3136997209 hasAuthorship W3136997209A5012677128 @default.
- W3136997209 hasAuthorship W3136997209A5038194068 @default.
- W3136997209 hasAuthorship W3136997209A5057775904 @default.
- W3136997209 hasAuthorship W3136997209A5060974081 @default.
- W3136997209 hasAuthorship W3136997209A5076334542 @default.
- W3136997209 hasBestOaLocation W31369972091 @default.
- W3136997209 hasConcept C121332964 @default.
- W3136997209 hasConcept C123669783 @default.
- W3136997209 hasConcept C145148216 @default.
- W3136997209 hasConcept C147789679 @default.
- W3136997209 hasConcept C148898269 @default.
- W3136997209 hasConcept C17525397 @default.
- W3136997209 hasConcept C178790620 @default.
- W3136997209 hasConcept C179104552 @default.
- W3136997209 hasConcept C184651966 @default.
- W3136997209 hasConcept C185592680 @default.
- W3136997209 hasConcept C2779651331 @default.
- W3136997209 hasConcept C2780709120 @default.
- W3136997209 hasConcept C52859227 @default.
- W3136997209 hasConcept C55493867 @default.
- W3136997209 hasConcept C55904794 @default.
- W3136997209 hasConcept C62520636 @default.
- W3136997209 hasConcept C68801617 @default.
- W3136997209 hasConcept C7070889 @default.
- W3136997209 hasConcept C93391505 @default.
- W3136997209 hasConceptScore W3136997209C121332964 @default.
- W3136997209 hasConceptScore W3136997209C123669783 @default.
- W3136997209 hasConceptScore W3136997209C145148216 @default.
- W3136997209 hasConceptScore W3136997209C147789679 @default.
- W3136997209 hasConceptScore W3136997209C148898269 @default.
- W3136997209 hasConceptScore W3136997209C17525397 @default.
- W3136997209 hasConceptScore W3136997209C178790620 @default.
- W3136997209 hasConceptScore W3136997209C179104552 @default.
- W3136997209 hasConceptScore W3136997209C184651966 @default.
- W3136997209 hasConceptScore W3136997209C185592680 @default.
- W3136997209 hasConceptScore W3136997209C2779651331 @default.
- W3136997209 hasConceptScore W3136997209C2780709120 @default.
- W3136997209 hasConceptScore W3136997209C52859227 @default.
- W3136997209 hasConceptScore W3136997209C55493867 @default.
- W3136997209 hasConceptScore W3136997209C55904794 @default.
- W3136997209 hasConceptScore W3136997209C62520636 @default.
- W3136997209 hasConceptScore W3136997209C68801617 @default.
- W3136997209 hasConceptScore W3136997209C7070889 @default.