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- W3137029642 endingPage "108569" @default.
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- W3137029642 abstract "Four novel compounds, {[Zn(bmb)(NO3)]2}n (1), {[Co(bmb)(BDC)]2}n (2), {[Zn3(bmb)3(TDC)]}n (3) and {[Co3(bmb)3(TDC)]}n (4) (bmb = 1,4-bis((1H-benzo[d]imidazole −1-yl)methyl)benzene, H2BDC = p-phthalic acid, H3TDC = 1,3,5-benzenetricarboxylic) are synthesized via solvothermal method. Single crystal X-ray diffraction analysis shows that compound 1, 2 and 3, 4 exist in monoclinic crystal system, and P21/c, C2 and C2/c (3 and 4) space group respectively. Interestingly, the ligand in four compounds appears Cis and Trans configurations, which induces different structure of 1 (one-dimension) and 2,3,4 (three-dimension). Fluorescence analysis reveals that the emission wavelength of compound 1,2,3 and 4 arise at 475 nm, 425 nm, 440 nm and 438 nm respectively, which indicates that they can be acted as potential blue-purple luminescent materials. The effect of metal ions on fluorescence of compound 2 shows that Fe3+ and Cu2+ have quenching effect on fluorescence. In addition, compounds (1,3,4) are positive dielectrics. In terms of thermo-gravimetric analysis, the chemical structures of four compounds are relatively stable below 350 °C." @default.
- W3137029642 created "2021-03-29" @default.
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- W3137029642 date "2021-06-01" @default.
- W3137029642 modified "2023-09-27" @default.
- W3137029642 title "Synthesis, characterization and properties of four complexes based on semi-rigid bisbenzimidazole and aromatic carboxylic acid" @default.
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- W3137029642 doi "https://doi.org/10.1016/j.inoche.2021.108569" @default.
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