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• W3137159690 abstract "A modular synthetic approach toward diverse analogues of the far-red fluorophore silicon-rhodamine (SiR), based on a regioselective double nucleophilic addition of aryllanthanum reagents to esters, anhydrides, and lactones, is proposed. The reaction has improved functional group tolerance and represents a unified strategy toward cell-permeant, spontaneously blinking, and photoactivatable SiR fluorescent labels. In tandem with Pd-catalyzed hydroxy- or aminocarbonylation, it serves a streamlined synthetic pathway to a series of validated live-cell-compatible fluorescent dyes." @default.
• W3137159690 created "2021-03-29" @default.
• W3137159690 creator A5063704229 @default.
• W3137159690 date "2021-03-15" @default.
• W3137159690 modified "2023-09-23" @default.
• W3137159690 title "Modular Synthetic Approach to Silicon-Rhodamine Homologues and Analogues via Bis-aryllanthanum Reagents" @default.
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• W3137159690 doi "https://doi.org/10.1021/acs.orglett.1c00512" @default.
• W3137159690 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8041385" @default.
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• W3137159690 hasPublicationYear "2021" @default.
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