Matches in SemOpenAlex for { <https://semopenalex.org/work/W3137539130> ?p ?o ?g. }
- W3137539130 endingPage "130289" @default.
- W3137539130 startingPage "130289" @default.
- W3137539130 abstract "Four isostructural lanthanide coordination complexes based on 3,7-diamino-9,10-anthraquinone-2,6-disulfonate (dianionic, L) have been synthesized by hydrothermal method, namely [Er(L)(H2O)6]•[Er(H2O)8]•2L•8H2O (Er-L), [Tm(L)(H2O)6]•[Tm(H2O)8]•2L•8.5H2O (Tm-L), [Yb(L)(H2O)6]•[Yb(H2O)8]•2L•9H2O (Yb-L), [Lu(L)(H2O)6]•[Lu(H2O)8]•2L•9H2O (Lu-L). Single-crystal X-ray analysis reveals the existence of both coordinated and free ligand L in the crystal structure. Versatile sulfonate groups on these distinct L ligands, together with very rich coordinated and lattice water molecules, form a lot of hydrogen-bonding motifs that contribute to the stabilization of the crystal packing. It is interesting that the ligands stack into columns through strong π-π interactions and the centroid-centroid distances are between 3.281 and 3.331 Å. These ligands are stacked in an alternate off-set mode to avoid the steric hindrance between the bulky sulfonate groups, generating a repeated structural unit involving six stacked ligands. These lanthanide complexes proved to be good heterogeneous photocatalyst for promoting the visible-light driving photooxidation reactions of diarylacetylenes and thioethers. The Er-L complex exhibited the best catalytic activity and showed good catalytic efficiency over a wide range of substrates for both reaction systems. The Er-L photocatalyst can be easily isolated by simple filtration as crystalline material upon completion of the photooxidation reaction without structure change, and can be recycled for at least five catalytic cycles with persistent catalytic efficiency without any need of activation or regeneration. This family of lanthanide complexes represent a category of promising heterogeneous photocatalysts in terms of green chemistry, with the potential of promoting organic transformations highly efficiently under the irradiation of visible light." @default.
- W3137539130 created "2021-03-29" @default.
- W3137539130 creator A5009067426 @default.
- W3137539130 creator A5012444743 @default.
- W3137539130 creator A5021671870 @default.
- W3137539130 creator A5028009429 @default.
- W3137539130 creator A5050700976 @default.
- W3137539130 creator A5052122284 @default.
- W3137539130 creator A5056383870 @default.
- W3137539130 creator A5065172118 @default.
- W3137539130 creator A5075540220 @default.
- W3137539130 date "2021-07-01" @default.
- W3137539130 modified "2023-10-16" @default.
- W3137539130 title "Lanthanide complexes based on an anthraquinone derivative ligand and applications as photocatalysts for visible-light driving photooxidation reactions" @default.
- W3137539130 cites W1967461285 @default.
- W3137539130 cites W1974989346 @default.
- W3137539130 cites W1995004090 @default.
- W3137539130 cites W1996941025 @default.
- W3137539130 cites W1997470112 @default.
- W3137539130 cites W2004550299 @default.
- W3137539130 cites W2031142152 @default.
- W3137539130 cites W2041836479 @default.
- W3137539130 cites W2043596269 @default.
- W3137539130 cites W2059205366 @default.
- W3137539130 cites W2078122806 @default.
- W3137539130 cites W2085325281 @default.
- W3137539130 cites W2095287593 @default.
- W3137539130 cites W2132454074 @default.
- W3137539130 cites W2136803810 @default.
- W3137539130 cites W2148260760 @default.
- W3137539130 cites W2151324344 @default.
- W3137539130 cites W2267223424 @default.
- W3137539130 cites W2295840750 @default.
- W3137539130 cites W2315230973 @default.
- W3137539130 cites W2331860355 @default.
- W3137539130 cites W2424993258 @default.
- W3137539130 cites W2525192902 @default.
- W3137539130 cites W2530622057 @default.
- W3137539130 cites W2531824626 @default.
- W3137539130 cites W2588265396 @default.
- W3137539130 cites W2600463662 @default.
- W3137539130 cites W2617009200 @default.
- W3137539130 cites W2618127528 @default.
- W3137539130 cites W2761599994 @default.
- W3137539130 cites W2797148973 @default.
- W3137539130 cites W2799545202 @default.
- W3137539130 cites W2801154220 @default.
- W3137539130 cites W2808812378 @default.
- W3137539130 cites W2883042906 @default.
- W3137539130 cites W2896013716 @default.
- W3137539130 cites W2898516497 @default.
- W3137539130 cites W2900777486 @default.
- W3137539130 cites W2911305013 @default.
- W3137539130 cites W2912759559 @default.
- W3137539130 cites W2915668383 @default.
- W3137539130 cites W2936388882 @default.
- W3137539130 cites W2937653869 @default.
- W3137539130 cites W2953126464 @default.
- W3137539130 cites W2956156135 @default.
- W3137539130 cites W2974730708 @default.
- W3137539130 cites W2989071225 @default.
- W3137539130 cites W2995932077 @default.
- W3137539130 cites W3001657240 @default.
- W3137539130 cites W3004327229 @default.
- W3137539130 cites W3008993162 @default.
- W3137539130 cites W3022699137 @default.
- W3137539130 cites W3029051975 @default.
- W3137539130 cites W3047181836 @default.
- W3137539130 doi "https://doi.org/10.1016/j.molstruc.2021.130289" @default.
- W3137539130 hasPublicationYear "2021" @default.
- W3137539130 type Work @default.
- W3137539130 sameAs 3137539130 @default.
- W3137539130 citedByCount "1" @default.
- W3137539130 countsByYear W31375391302022 @default.
- W3137539130 crossrefType "journal-article" @default.
- W3137539130 hasAuthorship W3137539130A5009067426 @default.
- W3137539130 hasAuthorship W3137539130A5012444743 @default.
- W3137539130 hasAuthorship W3137539130A5021671870 @default.
- W3137539130 hasAuthorship W3137539130A5028009429 @default.
- W3137539130 hasAuthorship W3137539130A5050700976 @default.
- W3137539130 hasAuthorship W3137539130A5052122284 @default.
- W3137539130 hasAuthorship W3137539130A5056383870 @default.
- W3137539130 hasAuthorship W3137539130A5065172118 @default.
- W3137539130 hasAuthorship W3137539130A5075540220 @default.
- W3137539130 hasConcept C115624301 @default.
- W3137539130 hasConcept C116569031 @default.
- W3137539130 hasConcept C145148216 @default.
- W3137539130 hasConcept C161790260 @default.
- W3137539130 hasConcept C170493617 @default.
- W3137539130 hasConcept C178790620 @default.
- W3137539130 hasConcept C185592680 @default.
- W3137539130 hasConcept C201194858 @default.
- W3137539130 hasConcept C201770740 @default.
- W3137539130 hasConcept C205188671 @default.
- W3137539130 hasConcept C2778894819 @default.
- W3137539130 hasConcept C2778913731 @default.
- W3137539130 hasConcept C32909587 @default.
- W3137539130 hasConcept C537181965 @default.