FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3137649865> ?p ?o ?g. }

• W3137649865 endingPage "130326" @default.
• W3137649865 startingPage "130326" @default.
• W3137649865 abstract "The chiral-at-metal, piano-stool ruthenium(II) racemic organometallic [Ru(cymene)(chalconato)(pyridine)]PF6 was prepared by a multistep solution synthesis and its molecular and crystal structure was determined by single crystal X-ray diffraction. The compound crystallizes in a centrosymmetric triclinic P-1 space group with two molecules of opposite chirality within the asymmetric unit. Ruthenium is embedded in an octahedral half-sandwich coordination environment with four different donors, which generates the chirality of the metal centre. The formation of the organometallic was monitored ex-situ by infrared spectroscopy. The pyridine coordination to Ru(II) was particularly analysed to find its characteristic marker bands. The complex was also characterized by elemental analysis and NMR spectroscopy in solution. Its interaction with CT DNA and bovine serum albumin (BSA) was investigated by electron spectroscopy and spectrofluorimetry. The organometallic binds to DNA predominantly by electrostatic forces with low Kb value. On the contrary, its high affinity for BSA was confirmed by strong fluorescence quenching. The synchronous emission spectra revealed that the microenvironment of tryptophan is more affected compared to the environment of tyrosine." @default.
• W3137649865 created "2021-03-29" @default.
• W3137649865 creator A5004383301 @default.
• W3137649865 creator A5017323427 @default.
• W3137649865 creator A5061862882 @default.
• W3137649865 creator A5070341016 @default.
• W3137649865 date "2021-07-01" @default.
• W3137649865 modified "2023-10-01" @default.
• W3137649865 title "Low DNA and high BSA binding affinity of cationic ruthenium(II) organometallic featuring pyridine and 2’-hydroxychalcone ligands" @default.
• W3137649865 cites W1895316964 @default.
• W3137649865 cites W1963719070 @default.
• W3137649865 cites W1971586346 @default.
• W3137649865 cites W1979368277 @default.
• W3137649865 cites W1986349622 @default.
• W3137649865 cites W1988007606 @default.
• W3137649865 cites W2006212665 @default.
• W3137649865 cites W2006953370 @default.
• W3137649865 cites W2008002124 @default.
• W3137649865 cites W2008166938 @default.
• W3137649865 cites W2010820829 @default.
• W3137649865 cites W2017162330 @default.
• W3137649865 cites W2027560251 @default.
• W3137649865 cites W2030844952 @default.
• W3137649865 cites W2030864703 @default.
• W3137649865 cites W2034735042 @default.
• W3137649865 cites W2034947652 @default.
• W3137649865 cites W2036913447 @default.
• W3137649865 cites W2039259521 @default.
• W3137649865 cites W2039597106 @default.
• W3137649865 cites W2045464802 @default.
• W3137649865 cites W2048447619 @default.
• W3137649865 cites W2051730223 @default.
• W3137649865 cites W2053883744 @default.
• W3137649865 cites W2059338123 @default.
• W3137649865 cites W2063334178 @default.
• W3137649865 cites W2065402334 @default.
• W3137649865 cites W2065981852 @default.
• W3137649865 cites W2067294686 @default.
• W3137649865 cites W2069305922 @default.
• W3137649865 cites W2076497239 @default.
• W3137649865 cites W2091746210 @default.
• W3137649865 cites W2094630676 @default.
• W3137649865 cites W2116326663 @default.
• W3137649865 cites W2118779086 @default.
• W3137649865 cites W2129213133 @default.
• W3137649865 cites W2135281109 @default.
• W3137649865 cites W2137045520 @default.
• W3137649865 cites W2145538332 @default.
• W3137649865 cites W2167229423 @default.
• W3137649865 cites W2169503921 @default.
• W3137649865 cites W2253765134 @default.
• W3137649865 cites W2328411799 @default.
• W3137649865 cites W2331531468 @default.
• W3137649865 cites W2512976367 @default.
• W3137649865 cites W2520732091 @default.
• W3137649865 cites W2549078338 @default.
• W3137649865 cites W2558450903 @default.
• W3137649865 cites W2573748267 @default.
• W3137649865 cites W2611908977 @default.
• W3137649865 cites W2768159253 @default.
• W3137649865 cites W2769018834 @default.
• W3137649865 cites W2785900358 @default.
• W3137649865 cites W2918258626 @default.
• W3137649865 cites W2925296528 @default.
• W3137649865 cites W2945041466 @default.
• W3137649865 cites W2986557882 @default.
• W3137649865 cites W966381494 @default.
• W3137649865 doi "https://doi.org/10.1016/j.molstruc.2021.130326" @default.
• W3137649865 hasPublicationYear "2021" @default.
• W3137649865 type Work @default.
• W3137649865 sameAs 3137649865 @default.
• W3137649865 citedByCount "6" @default.
• W3137649865 countsByYear W31376498652022 @default.
• W3137649865 countsByYear W31376498652023 @default.
• W3137649865 crossrefType "journal-article" @default.
• W3137649865 hasAuthorship W3137649865A5004383301 @default.
• W3137649865 hasAuthorship W3137649865A5017323427 @default.
• W3137649865 hasAuthorship W3137649865A5061862882 @default.
• W3137649865 hasAuthorship W3137649865A5070341016 @default.
• W3137649865 hasConcept C121332964 @default.
• W3137649865 hasConcept C124668440 @default.
• W3137649865 hasConcept C155647269 @default.
• W3137649865 hasConcept C161790260 @default.
• W3137649865 hasConcept C178790620 @default.
• W3137649865 hasConcept C185592680 @default.
• W3137649865 hasConcept C20621625 @default.
• W3137649865 hasConcept C2779485729 @default.
• W3137649865 hasConcept C32909587 @default.
• W3137649865 hasConcept C52703039 @default.
• W3137649865 hasConcept C55493867 @default.
• W3137649865 hasConcept C555196967 @default.
• W3137649865 hasConcept C62520636 @default.
• W3137649865 hasConcept C71240020 @default.
• W3137649865 hasConcept C75473681 @default.
• W3137649865 hasConcept C7602139 @default.
• W3137649865 hasConcept C8010536 @default.
• W3137649865 hasConcept C86807702 @default.
• W3137649865 hasConcept C91967747 @default.

• next