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- W3137689802 abstract "Abstract Covalent functionalization of two‐dimensional molybdenum disulfide (2D MoS 2 ) holds great promise in developing robust organic‐MoS 2 hybrid structures. Herein, for the first time, we demonstrate an approach to building up a bisfunctionalized MoS 2 hybrid structure through successively reacting activated MoS 2 with alkyl iodide and aryl diazonium salts. This approach can be utilized to modify both colloidal and substrate supported MoS 2 nanosheets. We have discovered that compared to the adducts formed through the reactions of MoS 2 with diazonium salts, those formed through the reactions of MoS 2 with alkyl iodides display higher reactivity towards further reactions with electrophiles. We are convinced that our systematic study on the formation and reactivity of covalently functionalized MoS 2 hybrids will provide some practical guidance on multi‐angle tailoring of the properties of 2D MoS 2 for various potential applications." @default.
- W3137689802 created "2021-03-29" @default.
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- W3137689802 date "2021-05-07" @default.
- W3137689802 modified "2023-10-15" @default.
- W3137689802 title "Covalent Bisfunctionalization of Two‐Dimensional Molybdenum Disulfide" @default.
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- W3137689802 doi "https://doi.org/10.1002/anie.202103353" @default.
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