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• W3137694998 abstract "Abstract In this work, flame retarding phosphonate‐functionalized imidazolium ionic liquids (PFILs) were synthesized and employed as electrolyte additives for Li/LiFePO 4 half‐cells. Physical and electrochemical properties, including ionic conductivity, electrochemical properties, electrochemical oxidation limit, electrochemical impedance spectroscopy (EIS) and lithium‐ion transference number (T Li + ), were investigated. The results demonstrate that the addition of PFIL can improve the electrochemical performance of lithium‐ion batteries (LIBs). Hybrid electrolyte with 10 wt % bidentate phosphonate‐functionalized imidazolium ionic liquid (b‐PFIL) exhibits more excellent electrochemical oxidation stability (up to 4.77 V vs. Li/Li + ), capacity retention (87.3 % after 400 cycles) and rate capability. These improvements can be ascribed to the enhanced lithium‐ion transference number (T Li + ), which results from the stronger binding affinity between chelating b‐PFIL and LiPF 6 ." @default.
• W3137694998 created "2021-03-29" @default.
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• W3137694998 date "2021-03-10" @default.
• W3137694998 modified "2023-09-23" @default.
• W3137694998 title "Bidentate Phosphonate‐Functionalized Ionic Liquid Exhibiting Better Ability in Improving the Performance of Lithium‐Ion Battery" @default.
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• W3137694998 doi "https://doi.org/10.1002/slct.202004804" @default.
• W3137694998 hasPublicationYear "2021" @default.
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