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• W3137757432 startingPage "1931" @default.
• W3137757432 abstract "Abstract Several strategies for the development of the synthesis of P‐chiral organophosphorus compounds with (L)‐prolinol as a source of chirality have been examined. A reaction of L ‐prolinol with a set of different alkyl/arylphosphonous acid diamides led in most of the cases to the quantitative formation of the appropriate bicyclic oxazaphospholidines with complete diastereo and enantioselectivity. The latter were reacted with BH 3 complex and the formed borane analogues were submitted to structural modifications leading to tertiary phosphine‐boranes. Additionally, the effectiveness of oxazaphospholidines as ligands in transition metal asymmetric catalysis has been tested in hydrogenation of dehydroaminoacid esters and imine." @default.
• W3137757432 created "2021-03-29" @default.
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• W3137757432 date "2021-03-24" @default.
• W3137757432 modified "2023-10-03" @default.
• W3137757432 title "Prolinol as a Chiral Auxiliary in Organophosphorus Chemistry" @default.
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• W3137757432 doi "https://doi.org/10.1002/ejoc.202100196" @default.
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