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• W3137831272 abstract "Abstract Copper-hydrides have been intensively studied for a long time due to their utilization in a variety of technologically important chemical transformations. Nevertheless, poor stability of the species severely hinders its isolation, storage and operation, which is worse for nano-sized ones. We report here an unprecedented strategy to access to ultrastable copper-hydride nanoclusters (NCs), namely, using bidentate N-heterocyclic carbenes as stabilizing ligands in addition to thiolates. In this work, a simple synthetic protocol was developed to synthesize the first large copper-hydride nanoclusters (NCs) stabilized by N-heterocyclic carbenes (NHCs). The NC, with the formula of Cu 31 (RS) 25 (NHC) 3 H 6 (NHC = 1,4-bis(1-benzyl-1H-benzimidazol-1-ium-3-yl) butane, RS = 4-fluorothiophenol), was fully characterized by high resolution Fourier transform ion cyclotron resonance mass spectrum, nuclear magnetic resonance, ultra-violet visible spectroscopy, density functional theory (DFT) calculations and single-crystal X-ray crystallography. Structurally, the title cluster exhibits unprecedented Cu 4 tetrahedron-based vertex-sharing (TBVS) superstructure (fusion of six Cu 4 tetrahedra). Moreover, the ultrahigh thermal stability renders the cluster a model system to highlight the power of NHCs (even other carbenes) in controlling geometrical, electronic and surface structure of polyhydrido copper clusters." @default.
• W3137831272 created "2021-03-29" @default.
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• W3137831272 date "2021-03-23" @default.
• W3137831272 modified "2023-10-15" @default.
• W3137831272 title "Copper-hydride nanoclusters with enhanced stability by N-heterocyclic carbenes" @default.
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• W3137831272 doi "https://doi.org/10.1007/s12274-021-3389-9" @default.
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