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- W3137926972 abstract "Ultrathin Tb 3+ -doped Zinc metal-organic-framework two-dimensional (2D) nanosheets (Tb 3+ @Zn-AIP-NS, AIP = 5-aminoisophthalic acid) were synthesized by an ultrasonic exfoliation method at room temperature, employing Tb 3+ @Zn-AIP microrods prepared in advance as the raw material. Experiments revealed that the as-prepared ultrathin Tb 3+ @Zn-AIP-NS could be dispersed homogeneously in deionized water to obtain a stable sol, and emit the strong characteristic fluorescence of Tb 3+ ions. Since the above strong luminescence of Tb 3+ ions was quenched by nitrofurazone (NFZ) antibiotic without the interference from other antibiotics, anions, cations and amino acids in aqueous systems, the ultrathin Tb 3+ @Zn-AIP-NS could be employed as a sensitive probe for visualized fluorescence detection of NFZ with a high K sv of 4.59 × 10 5 M −1 , a low LOD of 0.24 μM and a quick response time of 20 s. Systematic investigations on the sensing mechanism suggested that the synergistic action between the inner filter effect and the fluorescence resonance energy transfer resulted in the selective detection of NFZ. Moreover, the practical application of the present Tb 3+ @Zn-AIP-NS sensor was also investigated. • Ultrathin Tb3+@Zn-AIP-NS is prepared by an ultrasonic exfoliation method at room temperature. • As-obtained Tb 3+ @Zn-AIP-NS can form stable sol in water and emit strong fluorescence. • Strong fluorescence of Tb 3+ @Zn-AIP-NS is sensitively and selectively quenched by nitrofurazone. • Tb 3+ @Zn-AIP-NS sensor bears a far lower detection limit down to 0.24 μM for nitrofurazone." @default.
- W3137926972 created "2021-03-29" @default.
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- W3137926972 date "2021-06-01" @default.
- W3137926972 modified "2023-10-16" @default.
- W3137926972 title "Highly sensitive and visualized sensing of nitrofurazone on 2D Tb3+@Zn-AIP ultrathin nanosheets" @default.
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- W3137926972 doi "https://doi.org/10.1016/j.dyepig.2021.109309" @default.
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