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• W3137988319 abstract "Electrochemically active Metal-Organic Frameworks (MOFs) have been progressively recognized for their use in solar fuel production schemes. Typically, they are utilized as platforms for heterogeneous tethering of exceptionally large concentration of molecular electrocatalysts onto electrodes. Yet so far, the potential influence of their extraordinary chemical modularity on electrocatalysis has been overlooked. Herein, we demonstrate that, when assembled on a solid Ag CO2 reduction electrocatalyst, a non-catalytic UiO-66 MOF acts as a porous membrane that systematically tunes the active site's immediate chemical environment, leading to a drastic enhancement of electrocatalytic activity and selectivity. Electrochemical analysis shows that the MOF membrane improves catalytic performance through physical and electrostatic regulation of reactants delivery towards the catalytic sites. The MOF also stabilizes catalytic intermediates via modulation of active site's secondary coordination sphere. This concept can be expanded to a wide range of proton-coupled electrochemical reactions, providing new means for precise, molecular-level manipulation of heterogeneous solar fuels systems." @default.
• W3137988319 created "2021-03-29" @default.
• W3137988319 creator A5012607163 @default.
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• W3137988319 date "2021-05-05" @default.
• W3137988319 modified "2023-09-29" @default.
• W3137988319 title "Assembly of a Metal–Organic Framework (MOF) Membrane on a Solid Electrocatalyst: Introducing Molecular‐Level Control Over Heterogeneous CO ₂ Reduction" @default.
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• W3137988319 doi "https://doi.org/10.1002/anie.202102320" @default.
• W3137988319 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/8251703" @default.
• W3137988319 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33755294" @default.
• W3137988319 hasPublicationYear "2021" @default.
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