FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3138237927> ?p ?o ?g. }

• W3138237927 abstract "Abstract We recently reported a detailed investigation of the collision‐induced dissociation (CID) of [UO 2 (NO 3 ) 3 ] − and [UO 2 (NO 3 ) 2 (O 2 )] − in a linear ion trap mass spectrometer ( J. Mass Spectrom . DOI:10.1002/jms.4705). Here, we describe the CID of [UO 2 (NO 3 )(O 2 )] − which is created directly by ESI, or indirectly by simple elimination of O 2 from [UO 2 (NO 3 )(O 2 ) 2 ] − . CID of [UO 2 (NO 3 )(O 2 )] − creates product ions as at m/z 332 and m/z 318. The former may be formed directly by elimination of O 2 , while the latter required decomposition of a nitrate ligand and elimination of NO 2 . DFT calculations identify a pathway by which both product ions can be generated, which involves initial isomerization of [UO 2 (NO 3 )(O 2 )] − to create [UO 2 (O)(NO 2 )(O 2 )] − , from which elimination of NO 2 or O 2 will leave [UO 2 (O)(O 2 )] − or [UO 2 (O)(NO 2 )] − , respectively. For the latter product ion, the composition assignment of [UO 2 (O)(NO 2 )] − rather than [UO 2 (NO 3 )] − is supported by ion‐molecule reaction behavior, and in particular, the fact that spontaneous addition of O 2 , which is predicted to be the dominant reaction pathway for [UO 2 (NO 3 )] − is not observed. Instead, the species reacts with H 2 O, which is predicted to be the favored pathway for [UO 2 (O)(NO 2 )] − . This result in particular demonstrates the utility of ion‐molecule reactions to assist the determination of ion composition. As in our earlier study, we find that ions such as [UO 2 (O)(NO 2 )] − and [UO 2 (O)(O 2 )] − form H 2 O adducts, and calculations suggest these species spontaneously rearrange to create dihydroxides." @default.
• W3138237927 created "2021-03-29" @default.
• W3138237927 creator A5001417557 @default.
• W3138237927 creator A5026864306 @default.
• W3138237927 creator A5038615681 @default.
• W3138237927 creator A5053197575 @default.
• W3138237927 creator A5065461742 @default.
• W3138237927 date "2021-04-04" @default.
• W3138237927 modified "2023-10-17" @default.
• W3138237927 title "Collision‐induced dissociation of [UO ₂ (NO ₃ )(O ₂ )] ⁻ and reactions of product ions with H ₂ O and O ₂" @default.
• W3138237927 cites W1971819072 @default.
• W3138237927 cites W1975755749 @default.
• W3138237927 cites W1985310655 @default.
• W3138237927 cites W1991713655 @default.
• W3138237927 cites W2005798334 @default.
• W3138237927 cites W2008423326 @default.
• W3138237927 cites W2009523882 @default.
• W3138237927 cites W2023271753 @default.
• W3138237927 cites W2023390323 @default.
• W3138237927 cites W2039639109 @default.
• W3138237927 cites W2042980554 @default.
• W3138237927 cites W2050321400 @default.
• W3138237927 cites W2059044972 @default.
• W3138237927 cites W2066198423 @default.
• W3138237927 cites W2074415162 @default.
• W3138237927 cites W2081308950 @default.
• W3138237927 cites W2090135568 @default.
• W3138237927 cites W2094423254 @default.
• W3138237927 cites W2102108640 @default.
• W3138237927 cites W2143981217 @default.
• W3138237927 cites W2146268690 @default.
• W3138237927 cites W2148284063 @default.
• W3138237927 cites W2216508202 @default.
• W3138237927 cites W2313662443 @default.
• W3138237927 cites W2314895770 @default.
• W3138237927 cites W2331032609 @default.
• W3138237927 cites W2413658014 @default.
• W3138237927 cites W2470913428 @default.
• W3138237927 cites W2515115614 @default.
• W3138237927 cites W2592930272 @default.
• W3138237927 cites W2768799006 @default.
• W3138237927 cites W2796874128 @default.
• W3138237927 cites W2797121143 @default.
• W3138237927 cites W2969413176 @default.
• W3138237927 cites W3122640289 @default.
• W3138237927 cites W4549153 @default.
• W3138237927 doi "https://doi.org/10.1002/jms.4720" @default.
• W3138237927 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/33813763" @default.
• W3138237927 hasPublicationYear "2021" @default.
• W3138237927 type Work @default.
• W3138237927 sameAs 3138237927 @default.
• W3138237927 citedByCount "1" @default.
• W3138237927 countsByYear W31382379272023 @default.
• W3138237927 crossrefType "journal-article" @default.
• W3138237927 hasAuthorship W3138237927A5001417557 @default.
• W3138237927 hasAuthorship W3138237927A5026864306 @default.
• W3138237927 hasAuthorship W3138237927A5038615681 @default.
• W3138237927 hasAuthorship W3138237927A5053197575 @default.
• W3138237927 hasAuthorship W3138237927A5065461742 @default.
• W3138237927 hasConcept C102931765 @default.
• W3138237927 hasConcept C113196181 @default.
• W3138237927 hasConcept C126661725 @default.
• W3138237927 hasConcept C145148216 @default.
• W3138237927 hasConcept C147789679 @default.
• W3138237927 hasConcept C161790260 @default.
• W3138237927 hasConcept C162356407 @default.
• W3138237927 hasConcept C176107965 @default.
• W3138237927 hasConcept C178790620 @default.
• W3138237927 hasConcept C185592680 @default.
• W3138237927 hasConcept C31827203 @default.
• W3138237927 hasConcept C32909587 @default.
• W3138237927 hasConcept C43617362 @default.
• W3138237927 hasConcept C8010536 @default.
• W3138237927 hasConceptScore W3138237927C102931765 @default.
• W3138237927 hasConceptScore W3138237927C113196181 @default.
• W3138237927 hasConceptScore W3138237927C126661725 @default.
• W3138237927 hasConceptScore W3138237927C145148216 @default.
• W3138237927 hasConceptScore W3138237927C147789679 @default.
• W3138237927 hasConceptScore W3138237927C161790260 @default.
• W3138237927 hasConceptScore W3138237927C162356407 @default.
• W3138237927 hasConceptScore W3138237927C176107965 @default.
• W3138237927 hasConceptScore W3138237927C178790620 @default.
• W3138237927 hasConceptScore W3138237927C185592680 @default.
• W3138237927 hasConceptScore W3138237927C31827203 @default.
• W3138237927 hasConceptScore W3138237927C32909587 @default.
• W3138237927 hasConceptScore W3138237927C43617362 @default.
• W3138237927 hasConceptScore W3138237927C8010536 @default.
• W3138237927 hasFunder F4320306076 @default.
• W3138237927 hasFunder F4320311597 @default.
• W3138237927 hasIssue "5" @default.
• W3138237927 hasLocation W31382379271 @default.
• W3138237927 hasOpenAccess W3138237927 @default.
• W3138237927 hasPrimaryLocation W31382379271 @default.
• W3138237927 hasRelatedWork W1965789684 @default.
• W3138237927 hasRelatedWork W1966741770 @default.
• W3138237927 hasRelatedWork W1971682310 @default.
• W3138237927 hasRelatedWork W2016621240 @default.
• W3138237927 hasRelatedWork W2017438950 @default.
• W3138237927 hasRelatedWork W2018957170 @default.
• W3138237927 hasRelatedWork W2026642978 @default.

• next