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- W3138601265 abstract "The reaction of copper(II) sulfatepentahydrate with 2-nitrobenzoic acid and N , N , N ′, N ′-tetramethylethylenediamine (TMEDA) in basic solution produces the complex bis(2-nitrobenzoato-κ O )( N , N , N ′, N ′-tetramethylethylenediamine-κ 2 N , N ′)copper(II), [Cu(C 7 H 4 NO 4 ) 2 (C 6 H 16 N 2 )] or [Cu(2-nitrobenzoate) 2 (tmeda)]. Each carboxylate group of the 2-nitrobenzoate ligand is coordinated by Cu II atom in a monodentate fashion and two TMEDA ligand nitrogen atoms are coordinate by the metal center, giving rise to a distorted square-planar coordination environment. In the crystal, metal complexes are linked by centrosymmetric C—H...O hydrogen bonds, forming ribbons via a R 2 2 (10) ring motif. These ribbons are linked by further C—H...O hydrogen bonds, leading to two-dimensional hydrogen-bonded arrays parallel to the bc plane. Weak π–π stacking interactions provide additional stabilization of the crystal structure. Hirshfeld surface analysis, d norm and two-dimensional fingerprint plots were examined to verify the contributions of the different intermolecular contacts within the supramolecular structure. The major interactions of the complex are O...H/H...O (44.9%), H...H (34%) and C...H (14.5%)." @default.
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- W3138601265 date "2021-03-19" @default.
- W3138601265 modified "2023-09-27" @default.
- W3138601265 title "Crystal structure and Hirshfeld surface analysis of a copper(II) complex containing 2-nitrobenzoate and tetramethylethylenediamine ligands" @default.
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- W3138601265 doi "https://doi.org/10.1107/s2056989021002802" @default.
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