FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3138633434> ?p ?o ?g. }

• W3138633434 endingPage "1785" @default.
• W3138633434 startingPage "1776" @default.
• W3138633434 abstract "Abstract Reaction between NOSbF 6 and Cu(SbF 6 ) 2 in aHF yielded NOCu(SbF 6 ) 3 . In the presence of H 3 OSbF 6 , single crystals of (H 3 O) 0.2 (NO) 0.8 Cu(SbF 6 ) 3 were grown from a saturated aHF solution. Both salts are isotypic and crystallize in the orthorhombic space group Pnma (No. 62) at 200 K. The main feature of their crystal structures are rings of CuF 6 octahedra sharing apexes with SbF 6 octahedra connected into 3‐D network. Single charged cations are located inside the cavities. Reaction between 0.25NOSbF 6 , 0.75NO 2 SbF 6 and Cu(SbF 6 ) 2 in aHF yielded (NO) 0.25 (NO 2 ) 0.75 Cu(SbF 6 ) 3 upon the crystallization. It crystallizes in the cubic space group Im (No. 204) at 200 K. Subsequent experiments with M(SbF 6 ) 2 (M=Cu, Zn) showed that, when the NO + cations are partially or completely replaced by H 3 O + , the grown crystals of (H 3 O) 0.125 (NO) 0.125 (NO 2 ) 0.75 Zn(SbF 6 ) 3 and (H 3 O) 0.25 (NO 2 ) 0.75 M(SbF 6 ) 3 (M=Cu, Zn) are isotypic to (NO) 0.25 (NO 2 ) 0.75 Cu(SbF 6 ) 3 . Crystal structure of the latter demonstrates similar 3‐D structural motif as observed for the NOCu(SbF 6 ) 3 salt. The crystal structures of (H 3 O) 0.64 (NO 2 ) 0.36 CuF(SbF 6 ) 2 and [Cu(H 2 O) 6 ](SbF 6 ) 2 were also determined. Crystallizations of NOSbF 6 /O 2 SbF 6 were carried out in aHF in different molar ratios. The crystal structure determinations of grown single crystals showed that they have the composition (NO) x (O 2 ) 1‐x SbF 6 (x=0.17, 0.55 0.75) indicating that most likely all phases with x=0–1 exist. They are isotypic to NOSbF 6 ." @default.
• W3138633434 created "2021-03-29" @default.
• W3138633434 creator A5035429818 @default.
• W3138633434 creator A5063170106 @default.
• W3138633434 date "2021-04-29" @default.
• W3138633434 modified "2023-09-25" @default.
• W3138633434 title "Nitrosonium and Nitronium Salts of New Mixed‐Cation Hexafluoridoantimonates(V)" @default.
• W3138633434 cites W1523011843 @default.
• W3138633434 cites W1527425854 @default.
• W3138633434 cites W1535363244 @default.
• W3138633434 cites W1816510241 @default.
• W3138633434 cites W1929169134 @default.
• W3138633434 cites W1963779154 @default.
• W3138633434 cites W1969360633 @default.
• W3138633434 cites W1981737822 @default.
• W3138633434 cites W1985672036 @default.
• W3138633434 cites W1990170643 @default.
• W3138633434 cites W1994412962 @default.
• W3138633434 cites W1996843082 @default.
• W3138633434 cites W2001176915 @default.
• W3138633434 cites W2010098227 @default.
• W3138633434 cites W2011176844 @default.
• W3138633434 cites W2022479855 @default.
• W3138633434 cites W2025767790 @default.
• W3138633434 cites W2030387472 @default.
• W3138633434 cites W2033854913 @default.
• W3138633434 cites W2035041248 @default.
• W3138633434 cites W2045599373 @default.
• W3138633434 cites W2047109583 @default.
• W3138633434 cites W2055609146 @default.
• W3138633434 cites W2056000017 @default.
• W3138633434 cites W2056453014 @default.
• W3138633434 cites W2056792373 @default.
• W3138633434 cites W2057870297 @default.
• W3138633434 cites W2059205366 @default.
• W3138633434 cites W2061558108 @default.
• W3138633434 cites W2069341870 @default.
• W3138633434 cites W2078374889 @default.
• W3138633434 cites W2078408215 @default.
• W3138633434 cites W2085459763 @default.
• W3138633434 cites W2087580775 @default.
• W3138633434 cites W2090179398 @default.
• W3138633434 cites W2090979493 @default.
• W3138633434 cites W2093212571 @default.
• W3138633434 cites W2104640942 @default.
• W3138633434 cites W2104742556 @default.
• W3138633434 cites W2112621207 @default.
• W3138633434 cites W2113867574 @default.
• W3138633434 cites W2115536494 @default.
• W3138633434 cites W2120874476 @default.
• W3138633434 cites W2131350133 @default.
• W3138633434 cites W2132454074 @default.
• W3138633434 cites W2133646224 @default.
• W3138633434 cites W2144439474 @default.
• W3138633434 cites W2145538332 @default.
• W3138633434 cites W2165528549 @default.
• W3138633434 cites W2313203690 @default.
• W3138633434 cites W2398830991 @default.
• W3138633434 cites W2416584463 @default.
• W3138633434 cites W2474439184 @default.
• W3138633434 cites W2507356793 @default.
• W3138633434 cites W2560049498 @default.
• W3138633434 cites W2586597532 @default.
• W3138633434 cites W2754753726 @default.
• W3138633434 cites W2777018251 @default.
• W3138633434 cites W2796202611 @default.
• W3138633434 cites W2805287200 @default.
• W3138633434 cites W2890913378 @default.
• W3138633434 cites W2917448201 @default.
• W3138633434 cites W2949217834 @default.
• W3138633434 cites W2952843410 @default.
• W3138633434 cites W2953282860 @default.
• W3138633434 cites W2953310928 @default.
• W3138633434 cites W2995586855 @default.
• W3138633434 cites W2999891454 @default.
• W3138633434 cites W3024466649 @default.
• W3138633434 cites W3040242870 @default.
• W3138633434 cites W3043656372 @default.
• W3138633434 doi "https://doi.org/10.1002/ejic.202100139" @default.
• W3138633434 hasPublicationYear "2021" @default.
• W3138633434 type Work @default.
• W3138633434 sameAs 3138633434 @default.
• W3138633434 citedByCount "3" @default.
• W3138633434 countsByYear W31386334342021 @default.
• W3138633434 countsByYear W31386334342023 @default.
• W3138633434 crossrefType "journal-article" @default.
• W3138633434 hasAuthorship W3138633434A5035429818 @default.
• W3138633434 hasAuthorship W3138633434A5063170106 @default.
• W3138633434 hasConcept C115624301 @default.
• W3138633434 hasConcept C178790620 @default.
• W3138633434 hasConcept C179104552 @default.
• W3138633434 hasConcept C185592680 @default.
• W3138633434 hasConcept C198819137 @default.
• W3138633434 hasConcept C203036418 @default.
• W3138633434 hasConcept C37243968 @default.
• W3138633434 hasConcept C8010536 @default.
• W3138633434 hasConceptScore W3138633434C115624301 @default.
• W3138633434 hasConceptScore W3138633434C178790620 @default.

• next