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- W3138736449 abstract "Macrocycles that assemble into nanotubes exhibit emergent properties stemming from their low dimensionality, structural regularity, and distinct interior environments. We report a versatile strategy to synthesize diverse nanotube structures in a single, efficient reaction by using a conserved building block bearing a pyridine ring. Imine condensation of a 2,4,6-triphenylpyridine-based diamine with various aromatic dialdehydes yields chemically distinct pentagonal [5 + 5], hexagonal [3 + 3], and diamond-shaped [2 + 2] macrocycles depending on the substitution pattern of the aromatic dialdehyde monomer. Atomic force microscopy and in solvo X-ray diffraction demonstrate that protonation of the macrocycles under the mild conditions used for their synthesis drives assembly into high-aspect ratio nanotubes. Each of the pyridine-containing nanotube assemblies exhibited measurable proton conductivity by electrochemical impedance spectroscopy, with values as high as 10-3 S m-1 (90% R.H., 25 °C) that we attribute to differences in their internal pore sizes. This synthetic strategy represents a general method to access robust nanotube assemblies from a universal pyridine-containing monomer, which will enable systematic investigations of their emergent properties." @default.
- W3138736449 created "2021-03-29" @default.
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- W3138736449 date "2021-05-18" @default.
- W3138736449 modified "2023-10-15" @default.
- W3138736449 title "Diverse Proton-Conducting Nanotubes via a Tandem Macrocyclization and Assembly Strategy" @default.
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- W3138736449 doi "https://doi.org/10.1021/jacs.1c02789" @default.
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- W3138736449 hasPublicationYear "2021" @default.
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