Matches in SemOpenAlex for { <https://semopenalex.org/work/W3138870499> ?p ?o ?g. }
- W3138870499 endingPage "1623" @default.
- W3138870499 startingPage "1611" @default.
- W3138870499 abstract "Abstract Novel polybenzoxazine/polysilsesquioxane nanocomposites were synthesized with uniform and reproducible structural morphology, high T g , and good thermal stability. Polysilsesquioxane was oriented in a nanometer‐size lamellar structure. Benzoxazine monomer based on silane (BA‐3aptms) was synthesized by reaction between bisphenol A, 3‐(trimethoxysilyl)propylamine, and paraformaldehyde in a 1:2:4 molar ratio. Four experimental conditions of the two stage sol–gel process for polysilsesquioxane were studied, and their effect on the material characteristics investigated. In the first stage, hydrolysis was favored, while the second stage mostly consisted of condensation. The reaction condition with the longest hydrolysis time allowed the increase of the concentration of silanol units and the selective condensation, favoring the formation of a higher amount of cage‐like cyclic structures. In addition, this experimental procedure was well controlled so that the sol–gel and oxazine‐ring opening reactions were extremely reproducible from batch to batch. All processes were monitored by Fourier transform infrared spectroscopy (FTIR), thermogravimetric analysis and dynamic mechanical thermal analysis, scanning electron and transmission electron microscopies, and X‐ray diffraction. A chemometric approach based on a multivariate curve resolution model was applied to the FTIR spectra, which allowed the identification of four reaction components associated with the sol–gel and the curing processes." @default.
- W3138870499 created "2021-03-29" @default.
- W3138870499 creator A5009908060 @default.
- W3138870499 creator A5031331290 @default.
- W3138870499 creator A5067688925 @default.
- W3138870499 creator A5073494588 @default.
- W3138870499 date "2021-03-24" @default.
- W3138870499 modified "2023-10-14" @default.
- W3138870499 title "Tuning morphology of siloxane bond‐based polybenzoxazines by controlling the sol–gel and curing processes" @default.
- W3138870499 cites W1969608313 @default.
- W3138870499 cites W1980758293 @default.
- W3138870499 cites W1988415105 @default.
- W3138870499 cites W1991546869 @default.
- W3138870499 cites W1993419109 @default.
- W3138870499 cites W2001397289 @default.
- W3138870499 cites W2005959590 @default.
- W3138870499 cites W2009816363 @default.
- W3138870499 cites W2021016910 @default.
- W3138870499 cites W2029990501 @default.
- W3138870499 cites W2031230965 @default.
- W3138870499 cites W2039902016 @default.
- W3138870499 cites W2040780014 @default.
- W3138870499 cites W2047589938 @default.
- W3138870499 cites W2055299187 @default.
- W3138870499 cites W2060213527 @default.
- W3138870499 cites W2060329192 @default.
- W3138870499 cites W2071433050 @default.
- W3138870499 cites W2072752116 @default.
- W3138870499 cites W2080892641 @default.
- W3138870499 cites W2100334428 @default.
- W3138870499 cites W2110440166 @default.
- W3138870499 cites W2118392342 @default.
- W3138870499 cites W2218635931 @default.
- W3138870499 cites W2321168360 @default.
- W3138870499 cites W2328903050 @default.
- W3138870499 cites W2409949654 @default.
- W3138870499 cites W2577831924 @default.
- W3138870499 cites W2581944932 @default.
- W3138870499 cites W2582998334 @default.
- W3138870499 cites W2584816433 @default.
- W3138870499 cites W2782729437 @default.
- W3138870499 cites W2790710292 @default.
- W3138870499 cites W2791264462 @default.
- W3138870499 cites W2792702487 @default.
- W3138870499 cites W2792885786 @default.
- W3138870499 cites W2795445031 @default.
- W3138870499 cites W2883815467 @default.
- W3138870499 cites W2894147149 @default.
- W3138870499 cites W2900599712 @default.
- W3138870499 cites W2901435392 @default.
- W3138870499 cites W2902979619 @default.
- W3138870499 cites W2921626098 @default.
- W3138870499 cites W2946438738 @default.
- W3138870499 cites W2953161120 @default.
- W3138870499 cites W2961909590 @default.
- W3138870499 cites W2996675452 @default.
- W3138870499 cites W3003778336 @default.
- W3138870499 cites W3026629084 @default.
- W3138870499 cites W3031163161 @default.
- W3138870499 cites W3038281088 @default.
- W3138870499 cites W3044662461 @default.
- W3138870499 cites W3048590525 @default.
- W3138870499 cites W3072472931 @default.
- W3138870499 cites W3089013559 @default.
- W3138870499 cites W4232510125 @default.
- W3138870499 cites W48364762 @default.
- W3138870499 cites W586174148 @default.
- W3138870499 doi "https://doi.org/10.1002/pen.25684" @default.
- W3138870499 hasPublicationYear "2021" @default.
- W3138870499 type Work @default.
- W3138870499 sameAs 3138870499 @default.
- W3138870499 citedByCount "4" @default.
- W3138870499 countsByYear W31388704992021 @default.
- W3138870499 countsByYear W31388704992022 @default.
- W3138870499 countsByYear W31388704992023 @default.
- W3138870499 crossrefType "journal-article" @default.
- W3138870499 hasAuthorship W3138870499A5009908060 @default.
- W3138870499 hasAuthorship W3138870499A5031331290 @default.
- W3138870499 hasAuthorship W3138870499A5067688925 @default.
- W3138870499 hasAuthorship W3138870499A5073494588 @default.
- W3138870499 hasConcept C127413603 @default.
- W3138870499 hasConcept C132976073 @default.
- W3138870499 hasConcept C159985019 @default.
- W3138870499 hasConcept C160892712 @default.
- W3138870499 hasConcept C161790260 @default.
- W3138870499 hasConcept C171250308 @default.
- W3138870499 hasConcept C178790620 @default.
- W3138870499 hasConcept C185592680 @default.
- W3138870499 hasConcept C188027245 @default.
- W3138870499 hasConcept C192562407 @default.
- W3138870499 hasConcept C2776139660 @default.
- W3138870499 hasConcept C2777581007 @default.
- W3138870499 hasConcept C2778024649 @default.
- W3138870499 hasConcept C2779723377 @default.
- W3138870499 hasConcept C2781448156 @default.
- W3138870499 hasConcept C38398224 @default.
- W3138870499 hasConcept C42360764 @default.
- W3138870499 hasConcept C521977710 @default.