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- W3138959665 abstract "The title electron acceptors are planar molecules undergoing reversible two-stage one-electron reduction processes. In the crystal of selenadiazole derivative (1), tetrameric structure is formed by two kinds of chalcogen bond (ChB), which is further connected by ChB and weak hydrogen bond (WHB). Although sulfur analogue (2) has only weaker ChB, it crystallizes isomorphously to 1 forming ChB-tetramer, thus contribution from ChB is more dominant than WHB in determining the crystal packing, which is different from the corresponding tetracyanoquinodimethane analogues. The first members of dicyanoquinodiimine derivatives fused with a selenadiazole or a thiadiazole were prepared, which crystallize isomorphously forming tetrameric aggregates by chalcogen bond through C≡N…Se–N or C≡N…S–N contacts. Different from the corresponding tetracyanoquinodimethane derivatives, weak hydrogen bond involving C-H groups is less important for determining their crystal packing." @default.
- W3138959665 created "2021-03-29" @default.
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- W3138959665 date "2021-06-05" @default.
- W3138959665 modified "2023-09-26" @default.
- W3138959665 title "[1,2,5]Chalcogenadiazole-fused Dicyanonaphthoquinodiimines: Larger Contribution from Chalcogen Bond than Weak Hydrogen Bond in Determining Crystal Structures" @default.
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- W3138959665 doi "https://doi.org/10.1246/cl.210095" @default.
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