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- W3139081437 abstract "Abstract Chiral polymers are often prepared by two ways depending upon chiral monomers, chiral catalysts, and chiral auxiliaries which always come from organics: one is the enantio‐selective polymerization of prochiral or racemic monomers or polymerization of optically active monomers; and the other one is the molecular imprinting technique, which creates chiral recognition sites inside a densely cross‐linked polymer gel. Herein, a unique method for the synthesis of chiroptical cross‐linked polymers via radical polymerization of achiral divinyl monomers in the mediation of the inorganic chiral nanosilica is reported. The monomers that are cross‐linkable such as divinylbenzene (DVB) and N , N ′ ‐methylenebisacrylamide (MBA) are physically adsorbed onto chiral silica bundles and then polymerized by dispersion of those monomers/silica bundles in the presence of radical initiators. The products are characterized by SEM, FT‐IR, solid‐state 13 C NMR, TGA, and CD. Very interestingly, the cross‐linked polymers themselves obtained via final removal of the chiral silica show remarkable chiroptical activity with mirror relationship and can make achiral guest of porphyrin adsorbed on the polymers become optically active." @default.
- W3139081437 created "2021-03-29" @default.
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- W3139081437 date "2021-03-20" @default.
- W3139081437 modified "2023-09-23" @default.
- W3139081437 title "Chiroptical Cross‐Linked Polymers Grown via Radical Polymerization around Chiral Nanosilica" @default.
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- W3139081437 doi "https://doi.org/10.1002/macp.202000436" @default.
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