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• W3139125127 startingPage "2659" @default.
• W3139125127 abstract "We report for the first time that the imidate radical can be efficiently added to glycals to generate glycosyl radicals, based on which a general, toxic-reagent-free synthesis of C-glycosides of 2-deoxy-2-amino sugars has been developed. Complementary to previous strategies, the reaction is 1,2-trans-stereoselective and could use aryl alkenes as substrates. The late-stage functionalization and density functional theory calculations are reported." @default.
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• W3139125127 date "2021-03-18" @default.
• W3139125127 modified "2023-10-16" @default.
• W3139125127 title "1,2-<i>trans</i>-Stereoselective Synthesis of <i>C</i>-Glycosides of 2-Deoxy-2-amino-sugars Involving Glycosyl Radicals" @default.
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• W3139125127 doi "https://doi.org/10.1021/acs.orglett.1c00551" @default.
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• W3139125127 hasPublicationYear "2021" @default.
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