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• W3139249711 startingPage "5005" @default.
• W3139249711 abstract "In terms of recently documented references, the introduction of V═O units into porous MOF/COF frameworks can greatly improve their original performance and expand their application prospects due to a change in their electronegativity. In this work, by a cation-exchange strategy, a consummate combination of separate 4f [Tm2(CO2)8] SBUs and 3d [VIVO(H2O)2] units generated the functionalized porous metal–organic framework {(Me2NH2)2[VO(H2O)][Tm2(BDCP)2]·3DMF·3H2O}n (NUC-11), in which [Tm2(CO2)8] SBUs constitute the fundamental 3D host framework of {[Tm2](BDCP)2}n along with [VIVO(H2O)2] units being further docked on the inner wall of channels by covalent bonds. Significantly, NUC-11 represents the first example of V═O modified porous MOFs, in which uncoordinated carboxylic groups (−CO2H) further grasp the functional [VIVO(H2O)2] units on the initial basic skeleton along with the formation of covalent bonds as fixed ropes. Furthermore, activated samples of NUC-11 displayed a good catalytic performance for the chemical synthesis of carbonates from related epoxides and CO2 with high conversion rate. Moreover, by employing NUC-11 as a catalyst, a simulator of mustard gas, 2-chloroethyl ethyl sulfide, could be quickly and efficiently oxidized into low-toxicity products of oxidized sulfoxide (CEESO). Thus, this study offers a brand new view for the design and synthesis of functional-units-modified porous MOFs, which could be potentially applied as an excellent candidate in the growing field of efficient catalysis." @default.
• W3139249711 created "2021-03-29" @default.
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• W3139249711 date "2021-03-15" @default.
• W3139249711 modified "2023-10-17" @default.
• W3139249711 title "V═O Functionalized {Tm₂}–Organic Framework Designed by Postsynthesis Modification for Catalytic Chemical Fixation of CO₂ and Oxidation of Mustard Gas" @default.
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• W3139249711 doi "https://doi.org/10.1021/acs.inorgchem.1c00053" @default.
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• W3139249711 hasPublicationYear "2021" @default.
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