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- W3139322041 abstract "We present herein an unprecedented desymmetrization of meso 1,3-diones by enantioselective intermolecular condensation. Under the catalysis by a chiral phosphoric acid, a range of readily available 1,3-diones undergo reaction with hydrazines to produce cyclic and acyclic keto-hydrazones bearing an all-carbon quaternary center in high efficiency and enantioselectivity. These compounds are also highly versatile for the preparation of multifunctional building blocks and heterocycles in excellent stereoselectivity." @default.
- W3139322041 created "2021-03-29" @default.
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- W3139322041 date "2021-03-16" @default.
- W3139322041 modified "2023-10-15" @default.
- W3139322041 title "Desymmetrization of 1,3-Diones by Catalytic Enantioselective Condensation with Hydrazine" @default.
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- W3139322041 doi "https://doi.org/10.1021/jacs.1c01366" @default.
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