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- W3139501866 abstract "A straightforward synthetic methodology for the preparation of photochromic siloles based on the dithienylethene motif is developed. It relies upon an efficient palladium-catalyzed annulation reaction of a 2,3-bis(3-thienyl)-silirene with terminal alkynes in mild conditions. The reaction is functional group-tolerant and can be performed in high yields with a variety of functional terminal alkynes. It can even be extended to a polymeric polypropargylmethacrylamide (PPMA) substrate affording the corresponding photochromic polymer with different degree of photochromic unit incorporation by simply adjusting the polymer/ silirene stoichiometric ratio." @default.
- W3139501866 created "2021-03-29" @default.
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- W3139501866 date "2021-04-21" @default.
- W3139501866 modified "2023-09-24" @default.
- W3139501866 title "Dithienylethene‐Based Photochromic Siloles: A Straightforward and Divergent Synthetic Strategy" @default.
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- W3139501866 doi "https://doi.org/10.1002/anie.202102540" @default.
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