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- W3139926352 abstract "A bioorthogonal reaction between N,N-dialkylhydroxylamines and cyclooctynes is described. This reaction features a highly regioselective transformation between small, easily functionalizable reaction components with second-order rate constants reaching 84 M-1 s-1. The reaction is orthogonal to the inverse-electron demand Diels-Alder reactions between tetrazine and strained alkenes, and its components exhibit exquisite stability and chemoselectivity in cell lysate. This retro-Cope elimination reaction introduces a new member to the bioorthogonal reaction compendium outside the prolific class of cycloaddition reactions." @default.
- W3139926352 created "2021-04-13" @default.
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- W3139926352 date "2021-04-08" @default.
- W3139926352 modified "2023-10-02" @default.
- W3139926352 title "Bioorthogonal Retro-Cope Elimination Reaction of <i>N</i>,<i>N</i>-Dialkylhydroxylamines and Strained Alkynes" @default.
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- W3139926352 doi "https://doi.org/10.1021/jacs.1c00885" @default.
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