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- W3140100866 abstract "A three-dimensional coordination polymer [Mn2(μ1,3-N3)4(μ-PP)2]n(PP = 3-(pyra-zin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand,and its crystal structure was determined by X-ray crystallography.The crystal data:triclinic system,space group P,with a = 6.794(4),b = 9.885(6),c = 9.947(6) ,α = 64.170(6),β = 84.190(8),γ = 85.319(8)°,V = 597.7(6) 3,Z = 1,C18H14Mn2N18O2,Mr = 624.35,Dc = 1.735 g/cm3,F(000) = 314 and μ = 1.117 mm-1.In the crystal,the azide anion acts as a bridge ligand and makes adjacent Mn(II) ions connect into a two-dimensional sheet on the ab plane,then 3-(pyrazin-2-yloxy)-pyridine serves as a bidentate bridge ligand to connect neighboring sheets along the c axis,and finally a three-dimensional structure is formed." @default.
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- W3140100866 date "2008-01-01" @default.
- W3140100866 modified "2023-09-29" @default.
- W3140100866 title "Synthesis and Crystal Structure of a Three-dimensional Mn（II） Coordination Polymer with 3-（Pyrazin-2-yloxy）-pyridine and Azide Anion as Mixed Bridge Ligand" @default.
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