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- W3140344582 abstract "在一个不锈钢压热器，没有催化剂并且与包含 Zn 催化剂，从脲和甲醇的 dimethyl 碳酸盐(直接数字控制) 的合成动力学独立被调查。没有催化剂，为直接数字控制合成(有到甲基氨基甲酸酯(MC ) 的甲醇的脲的反应) 的第一反应，反应动力学能关于甲醇和脲的集中被描述为第一份订单。为直接数字控制合成(有到直接数字控制的甲醇的 MC 的反应) 的第二反应，结果展出零顺序的反应的特征。为包含 Zn 催化剂，自从它的率比第二反应快得多，第一反应在动力学模型被忽视。自从它减少，第二反应的宏运动的参数被适合试验性的数据到一个伪 homogenous 模型，处于良好的竟技状态直接数字控制的过程的方面反应在被合并获得直接数字控制的收益急速地在高温度。当直接数字控制的方面反应的是 135 kJ/mol 时，对直接数字控制的从 MC 的反应的激活精力是 104 kJ/mol。直接数字控制的最高的收益是 23% 。" @default.
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- W3140344582 date "2012-01-01" @default.
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- W3140344582 title "Macro kinetics for synthesis of dimethyl carbonate from urea and methanol on Zn-containing catalyst" @default.
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