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- W3140765636 abstract "Three new cobalt complexes, {[Co5(tci)2(bimb)3( 3-O)2(H2 O)2 ]·3DMF·4H2 O}n(1), {[Co3(tci)2(bib)]·2DMF·2H2 O}n(2) and {[Co(Htci)(bpea)0.5 ]·H2 O}n(3)(H3 tci = tris(2-carboxyethyl)isocyanurate, bimb = 4,4′-bis(imidazol-1-yl)biphenyl, bib = 1,4-bis(imidazol-1-yl)benzene, bpea = 1,2-bis(4-pyridyl)ethane, DMF = N,N′-dimethylformamide), have been successfully synthesized through the assembly of Co(II) ions, H3 tci and different N-donor ligands, respectively. All complexes were structurally characterized by single crystal X-ray diffraction, elemental analyses, IR spectra, thermogravimetric(TG) analyses and X-ray powder diffraction(XRPD). Complex 1 exhibits a 3D three-fold parallel interpenetrated 3D → 3D structure with(65·8) CdSO4 topology. Complex 2 is built from [Co3( 2-Ocarboxyl)2(CO2)4 ] clusters and linear bib ligands, displaying a two-fold parallel interpenetrated(3,8)-connected(43)2(46·618·84) topology, while complex 3 is a 3D pillar-layered structure involving an infinite –Co–( 2-Ocarboxyl)(CO2)–Co–chain. The diverse structures of the three complexes indicate that the skeletons of different N-donor ligands play an important role in the assembly of such different frameworks. In addition, magnetic investigation indicates that besides spin-orbit coupling of Co(II) ions, there exist antiferromagnetic exchange interactions in Co5 and Co3 clusters of 1 and 2, respectively." @default.
- W3140765636 created "2021-04-13" @default.
- W3140765636 creator A5012292041 @default.
- W3140765636 date "2013-01-01" @default.
- W3140765636 modified "2023-09-23" @default.
- W3140765636 title "Syntheses, structures and magnetic properties of three Co(II) coordination architectures based on a flexible multidentate carboxylate ligand and different N-donor ligands" @default.
- W3140765636 hasPublicationYear "2013" @default.
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