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- W3141024411 abstract "UV photodissociation of benzoyl chloride, Ph–CO–Cl, is associated with the loss of a chlorine atom. Here we excite benzoyl chloride to the S1, S2, and S3 excited states at 237, 253, 265, and 279.6 nm and detect the Cl photofragment by [1 + 1′] photoionization using 118.9 nm VUV radiation. The translational energy distribution of the Cl atom is measured by velocity map ion imaging. An isotropic image and a unimodal translational energy distribution are observed at all dissociation wavelengths, and a fraction of 18–20% of the excess energy is released into translation. The results indicate a dissociation that predominately proceeds from the vibrationally hot S0 ground state, although the observed translational energy release deviates significantly from a prior distribution. However, the impulsive model does also not represent the translational energy release. As a Cl/Cl* branching ratio of 9:1 or more is observed in one-color experiments at 235 nm, we conclude that direct dissociation from excited electronic states contributes only to a minor extent." @default.
- W3141024411 created "2021-04-13" @default.
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- W3141024411 date "2021-04-05" @default.
- W3141024411 modified "2023-10-17" @default.
- W3141024411 title "Photodissociation of Benzoyl Chloride: A Velocity Map Imaging Study Using VUV Detection of Chlorine Atoms" @default.
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- W3141024411 doi "https://doi.org/10.1021/acs.jpca.0c11236" @default.
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