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- W3141127092 abstract "Photoinduced intramolecular electron transfer (PIET) plays a vital role in the efficiency of electronics communication in transition metal complexes catalysing oxidation-reduction reaction. In this work, we theoretically calculate the rate of electron transfer(ET) in Ru(II)-BL-Ru(I) hybrid complexes; where BL is bridging ligand. A brief concept of ET in the basis of Marcus theory, which is extended to address a variety of different type of ET, is provided. We show that, in the case of Ru(II)-BL-Ru(I) complex, ET involves a non-adiabatic state which thanks to a fast electronics communication between donor and acceptor connected by BL and becomes rigid complex. Single electron transferring in Ru(II)-BL-Ru(I) complex governed by PIET constructed by potential energy curve as change of structural transformation over time-evolution. We also investigate the mechanism of PIET involving a redox reaction in excited state, wherein the oxidation state of Ru(II) (donor) and Ru(I) (acceptor) changes. To access non-adiabatic state of Ru(II)-BL-Ru(I), we use constrained density functional theory to allow ground state calculation to be performed along with geometry constraints. We also systematically study the role of distance of donor-acceptor separation on kinetics of PIET" @default.
- W3141127092 created "2021-04-13" @default.
- W3141127092 creator A5088530950 @default.
- W3141127092 date "2021-03-29" @default.
- W3141127092 modified "2023-09-27" @default.
- W3141127092 title "Electronics Communication and Photoinduced Intramolecular Electron Transfer in Hybrid Ru(II)-Re(I) Complexes Using Eigenstate-Based and Diabatic-State-Based Models" @default.
- W3141127092 doi "https://doi.org/10.26434/chemrxiv.14327177.v1" @default.
- W3141127092 hasPublicationYear "2021" @default.
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