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- W3141199686 abstract "benzaldehyde 的加氢是典型连续反应，自从中间的本甲基白酒是容易的是进一步的 hydrogenated。这里，我们证明本甲基酒精的选择能经由碳 nanotubes (CNT ) 的 functionalization 被调节，它被用作 Pd 的支持。与原来的 CNT，本甲基酒精的选择在 benzaldehyde 的 100% 变换是 88% 。与包含氧的组的介绍到 CNT 上，它落下到 27% 。相反，与 N 原子做 CNT，选择在一样的反应条件下面到达 96% 。运动学习证明本甲基酒精的加氢显著地被压制，它能被归因于本甲基酒精的削弱的吸附。这与经由和 functionalized CNT 的相互作用的 Pd 种类的修改电子结构有关是最可能的，作为由 XPS 出现描述。" @default.
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- W3141199686 date "2012-01-01" @default.
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- W3141199686 title "Selectivity modulation in the consecutive hydrogenation of benzaldehyde via functionalization of carbon nanotubes" @default.
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