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• W3141535279 abstract "The role of various vulcanizing systems on the curing characteristics, mechanical properties, morphology and dynamic mechanical analysis of natural rubber and recycled ethylene-propylene-diene rubber blends was investigated. Accelerated sulfur-vulcanizing systems (semi- EV and EV), peroxide, and mixed sulfur/peroxide-vulca- nizing systems (semi-EV/peroxide and EV/peroxide) were observed and compared. The blends were processed on a two-roll mill, and a fixed amount of carbon black was also incorporated. Amongst the blends, accelerated sulfur-vul- canizing systems exhibited higher torques, state of cure, tensile strength and elongation-at-break, in comparison with the peroxide-vulcanizing system, whereas the tensile mod- ulus, hardness and cross-link density showed lower trend. In the mixed sulfur/peroxide-vulcanizing systems, it showed intermediate behavior to the individual sulfur- or peroxide- vulcanizing systems. This was associated to the interference of peroxide during the cross-linking formation. SEM micrographs of semi-EV-vulcanizing system exhibited more roughness and cracking path indicating that higher energy was required towards the fractured surface. The high cross- link density observed from the swelling study could be verified from the storage modulus (E 0 ) where peroxide vulcanized blends provided a predominant degree of cross- linking followed by semi-EV, semi-EV/peroxide, EV and EV/peroxide-vulcanizing systems, respectively. The glass transition temperature (Tg) depicted at maximum peak of mechanical loss factor (tandmax), indicating that semi-EV- vulcanizing system showed highest Tg value. The Tg values can be ordered as semi-EV ( peroxide ( semi-EV/perox- ide ( EV ( EV/peroxide-vulcanizing systems. The Tg of rubber vulcanizates can be increased due to the restriction of molecular movement such as cross-link density." @default.
• W3141535279 created "2021-04-13" @default.
• W3141535279 creator A5057591604 @default.
• W3141535279 date "2014-01-01" @default.
• W3141535279 modified "2023-09-27" @default.
• W3141535279 title "Properties of natural rubber/recycled ethylene-propylene-diene rubber blends prepared using various vulcanizing systems" @default.
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