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- W314157439 abstract "The influence of the ratio e between the amounts of the two catalytic reagents, used to prepare Al(C 2 H 5 ) 3 /TiCl 4 catalysts, on styrene polymerization was studied by following the overall polymerization process in the time. With low e values, a cationic and a stereospecific anionic process occur simultaneously and independently. With increasing e values, above a certain limit the quantity of stereospecific catalyst, which is practically the only one formed, becomes independent of the amount of Al(C 2 H 5 ) 3 introduced, whose excess, however, causes aging of the catalyst during the time of polymerization, to an extent increasing with increasing e. In the first range of e values, the same catalyst is formed in smaller quantities, but it is stable during the polymerization time. Kinetic equations are eventually established, embracing all the experimental results." @default.
- W314157439 created "2016-06-24" @default.
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- W314157439 date "1967-01-01" @default.
- W314157439 modified "2023-09-27" @default.
- W314157439 title "STEREOSPECIFIC POLYMERIZATION OF STYRENE. NOTE IV: THE INFLUENCE OF THE CATALYTIC RATIO Al(C2H5)3/TiCl4" @default.
- W314157439 doi "https://doi.org/10.1016/b978-1-4831-9882-8.50015-4" @default.
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