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- W3141614832 abstract "Ag(I)X adsorbent was prepared with 13X zeolite as the adsorbent carrier by the method of liquid phase ion exchange.Thiophene,3-methylthiophene and 2,5-dimethylthiophene were used as the sulfur-containing compounds in model gasoline sample to investigate the adsorptive capacity and selectivity of Ag(I)X adsorbent for various sulfur compounds by the adsorption experiment in fixedbed,and the effects of toluene and cyclohexene on the adsorptive performance of Ag(I)X were also investigated.The adsorption mechanism of thiophenic compounds on Ag(I)X was analyzed.The results showed that Ag(I)X had high adsorptive capacity and selectivity for thiophenic compounds.Breakthrough adsorption capacities of Ag(I)X for thiophene,3-methylthiophene and 2,5-dimethylthiophene were 0.776,0.859 and 0.926 mg/g,respectively,which meant the selective adsorption order for them from big to small was 2,5-dimethylthiophene,3-methylthiophene and thiophene.The presence of toluene and cyclohexene in the model gasoline led to a reduction of total breakthrough adsorption capacity by 61% and 34%,respectively,which indicated that the competitive adsorption of toluene to thiophenic compounds was stronger than that of cyclohexene.Theπ-complexation mechanism could be used to interpret the differences in adsorption performances of Ag(I)X for different thiophenic compounds,as well as the competitive adsorption of toluene and cyclohexene to thiophenic compounds." @default.
- W3141614832 created "2021-04-13" @default.
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- W3141614832 date "2013-01-01" @default.
- W3141614832 modified "2023-09-28" @default.
- W3141614832 title "Selective Adsorption of Thiophenic Sulfur Compounds on Ag(I)X Adsorbent" @default.
- W3141614832 hasPublicationYear "2013" @default.
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