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• W3141717764 abstract "We present the first examples of tethered silanoxyiodination reactions of allylic alcohols. The products are useful silanediol organoiodide synthons and are formed with high regioselectivity and diastereocontrol. The reaction is scalable greater than 10-fold without loss of yield or selectivity. Furthermore, the products are starting materials for further transformations, including deiodination, C-N bond installation, epoxide synthesis, and desilylation. DFT calculations provide a basis for understanding the exquisite 6-endo selectivity of this silanoxyiodination reaction and show that the observed products are both kinetically and thermodynamically preferred." @default.
• W3141717764 created "2021-04-13" @default.
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• W3141717764 date "2021-06-15" @default.
• W3141717764 modified "2023-09-25" @default.
• W3141717764 title "Tethered Silanoxyiodination of Alkenes" @default.
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• W3141717764 doi "https://doi.org/10.1021/acs.joc.1c00872" @default.
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