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• W3141916713 endingPage "159675" @default.
• W3141916713 startingPage "159675" @default.
• W3141916713 abstract "Nanoporous metals show great potentials in various applications including catalysis, sensing, actuation and supercapacitors. The liquid Ga-assisted alloying/dealloying strategy is a feasible and scalable way to fabricate substrate-supported nanoporous metals. However, the influence of intrinsic alloying mode and mechanism on the formation and modulation of nanoporous structure has not been thoroughly explored before. In this work, after painting liquid Ga on Ag foil, both the bulk-like Ag3Ga (in the Ag-rich zone) and wire-like Ag3Ga (in the liquid Ga-rich zone) form owing to the interdiffusion of Ag and Ga atoms. Correspondingly, the bimodal wire-like and unimodal bulk-like nanoporous Ag is obtained because of the structure inheritance during dealloying. In addition, the thickness of alloy layer (nanoporous layer) versus mass loading of liquid Ga follows a good linear relationship. The in-situ X-ray diffraction of dealloying from Ag3Ga to nanoporous Ag illustrates no other intermetallic phase appears and the dealloying process can be described by the dissolution-surface diffusion model. More importantly, the substrate-supported nanoporous Ag exhibits excellent mechanical properties which are of great importance to the future applications of nanoporous metals." @default.
• W3141916713 created "2021-04-13" @default.
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• W3141916713 date "2021-08-01" @default.
• W3141916713 modified "2023-10-01" @default.
• W3141916713 title "Alloying/dealloying mechanisms, microstructural modulation and mechanical properties of nanoporous silver via a liquid metal-assisted alloying/dealloying strategy" @default.
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• W3141916713 doi "https://doi.org/10.1016/j.jallcom.2021.159675" @default.
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