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- W3142012578 abstract "amphiphilic multiarm 共聚物与 N- 通过商业地可得到的 hyperbranched 聚酯(Boltorn H40 ) 的修正被综合 ?-carbobenzoxy-L-Lysine N-carboxyanhydride (ZLys-NCA ) 。在与 N-Boc-phenylalanine (Boc- N Phe ) 和 deprotected 被压缩以后在 trifluoroacetic 酸(TFA ) 的 Boc 组,原来的终端氢氧根组被转变成氨基的组然后开始了 ZLys-NCA 的戒指洞聚合。吸水(L 离氨酸) 在保护的本甲基组被 HBr 答案在冰川的醋酸(33 wt%) 移开以后, poly 成功地是到 Boltorn H40 的表面的 grafted。产生 multiarm 共聚物被 1H-NMR, GPC 和 FTIR 描绘。NMR 和 GPC 分析计算的手臂长度分别地是为 H40-Phe-PLys1 和 H40-Phe-PLys2 的大约 3 和 13 离氨酸单位。由于 amphiphilic 分子的结构,他们显示了能力到进在有在到 250 nm 的从 70 nm 的范围的平均直径的水的答案的球形的微粒自我装配。分别地, H40-Phe-PLys1 和 H40-Phe-PLys2 的 CMC 是 0.013 mg/mL 和 0.028 mg/mL 与更短的手臂长度显示那 H40-Phe-PLys1 对更容易比有更长的手臂长度的 H40-Phe-PLys2 自我装配。" @default.
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- W3142012578 date "2011-01-01" @default.
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- W3142012578 title "THE AMPHIPHILIC MULTIARM COPOLYMERS BASED ON HYPERBRANCHED POLYESTER AND LYSINE:SYNTHESIS AND SELF-ASSEMBLY" @default.
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