Matches in SemOpenAlex for { <https://semopenalex.org/work/W3142882685> ?p ?o ?g. }
Showing items 1 to 84 of
84
with 100 items per page.
- W3142882685 endingPage "1331" @default.
- W3142882685 startingPage "1327" @default.
- W3142882685 abstract "Hydrogen evolution in the presence of atmospheric level of oxygen is a significant barrier in the quest for an alternative, sustainable and green source of energy to counter the depleting fossil fuel sources and increasing global warming due to fossil fuel burning. Oxygen reduction is thermodynamically more favourable than proton reduction and it often produces reactive oxygenated species upon partial reduction which deactivates the catalyst. Thus, catalyst development is required for efficient proton reduction in the presence of oxygen. Here, we demonstrate an iron porphyrin having triazole containing 2 nd sphere hydrogen bonding residues appended with redox active ferrocene moieties ( α 4 -Tetra-2-(3-ferrocenyl-1,2,3-triazolyl)phenylporphyrin (FeFc 4 )) as a bifunctional catalyst for fast and selective oxygen reduction to water and thus, preventing the proton reduction by the same catalyst from oxidative stress. Fe(0) is the active species for proton reduction in these iron porphyrin class of complexes and it is observed that the kinetics of proton reduction at Fe(0) state occurs at much faster rate than O 2 reduction and thus, paving the way for selective proton reduction in the presence of oxygen. Oxygen-tolerant proton reduction with an iron porphyrin having 2 nd sphere redox active ferrocene groups, FeFc 4 ." @default.
- W3142882685 created "2021-04-13" @default.
- W3142882685 creator A5006581742 @default.
- W3142882685 creator A5013392233 @default.
- W3142882685 creator A5020610169 @default.
- W3142882685 date "2021-08-01" @default.
- W3142882685 modified "2023-09-27" @default.
- W3142882685 title "Proton reduction in the presence of oxygen by iron porphyrin enabled with 2nd sphere redox active ferrocenes" @default.
- W3142882685 cites W1127985879 @default.
- W3142882685 cites W1966808626 @default.
- W3142882685 cites W1982685288 @default.
- W3142882685 cites W1990991656 @default.
- W3142882685 cites W2001892005 @default.
- W3142882685 cites W2016783049 @default.
- W3142882685 cites W2025845960 @default.
- W3142882685 cites W2035739033 @default.
- W3142882685 cites W2046896984 @default.
- W3142882685 cites W2065018748 @default.
- W3142882685 cites W2143332180 @default.
- W3142882685 cites W2215230320 @default.
- W3142882685 cites W2313172416 @default.
- W3142882685 cites W2313950842 @default.
- W3142882685 cites W2315816411 @default.
- W3142882685 cites W2324882829 @default.
- W3142882685 cites W2412704563 @default.
- W3142882685 cites W2414469619 @default.
- W3142882685 cites W2497948683 @default.
- W3142882685 cites W2549149855 @default.
- W3142882685 cites W2563363466 @default.
- W3142882685 cites W2587480966 @default.
- W3142882685 cites W2597732775 @default.
- W3142882685 cites W2617461485 @default.
- W3142882685 cites W2624834359 @default.
- W3142882685 cites W2802706006 @default.
- W3142882685 cites W2926214255 @default.
- W3142882685 cites W3030634732 @default.
- W3142882685 doi "https://doi.org/10.1016/s1872-2067(20)63761-5" @default.
- W3142882685 hasPublicationYear "2021" @default.
- W3142882685 type Work @default.
- W3142882685 sameAs 3142882685 @default.
- W3142882685 citedByCount "3" @default.
- W3142882685 countsByYear W31428826852022 @default.
- W3142882685 countsByYear W31428826852023 @default.
- W3142882685 crossrefType "journal-article" @default.
- W3142882685 hasAuthorship W3142882685A5006581742 @default.
- W3142882685 hasAuthorship W3142882685A5013392233 @default.
- W3142882685 hasAuthorship W3142882685A5020610169 @default.
- W3142882685 hasConcept C161790260 @default.
- W3142882685 hasConcept C178790620 @default.
- W3142882685 hasConcept C179104552 @default.
- W3142882685 hasConcept C185592680 @default.
- W3142882685 hasConcept C2779480358 @default.
- W3142882685 hasConcept C540031477 @default.
- W3142882685 hasConcept C55904794 @default.
- W3142882685 hasConcept C75473681 @default.
- W3142882685 hasConceptScore W3142882685C161790260 @default.
- W3142882685 hasConceptScore W3142882685C178790620 @default.
- W3142882685 hasConceptScore W3142882685C179104552 @default.
- W3142882685 hasConceptScore W3142882685C185592680 @default.
- W3142882685 hasConceptScore W3142882685C2779480358 @default.
- W3142882685 hasConceptScore W3142882685C540031477 @default.
- W3142882685 hasConceptScore W3142882685C55904794 @default.
- W3142882685 hasConceptScore W3142882685C75473681 @default.
- W3142882685 hasIssue "8" @default.
- W3142882685 hasLocation W31428826851 @default.
- W3142882685 hasOpenAccess W3142882685 @default.
- W3142882685 hasPrimaryLocation W31428826851 @default.
- W3142882685 hasRelatedWork W1986673804 @default.
- W3142882685 hasRelatedWork W1987234305 @default.
- W3142882685 hasRelatedWork W2005583882 @default.
- W3142882685 hasRelatedWork W2028651523 @default.
- W3142882685 hasRelatedWork W2061110197 @default.
- W3142882685 hasRelatedWork W2087330456 @default.
- W3142882685 hasRelatedWork W2092039007 @default.
- W3142882685 hasRelatedWork W2095739344 @default.
- W3142882685 hasRelatedWork W2403090021 @default.
- W3142882685 hasRelatedWork W2903716093 @default.
- W3142882685 hasVolume "42" @default.
- W3142882685 isParatext "false" @default.
- W3142882685 isRetracted "false" @default.
- W3142882685 magId "3142882685" @default.
- W3142882685 workType "article" @default.