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- W3142959746 abstract "A hydrophilic phosphinobiphenyl amidosulfonate, 2 0 -(dicyclohexylphosphino)-2- {((sulfonatomethyl)amino)carbonyl}(1,1 0 -biphenyl), triethylammonium salt (L2), was prepared and, together with its isomer bearing the polar amido-sulfonate tag in the position 4 of the biphenyl scaffold (compound L1), evaluated as a supporting ligand in Pd-catalyzed cyanation of aryl bromides using K4(Fe(CN)6) as the non-toxic cyanide source. The less sterically demanding ligand L1 was found to form more active catalysts than the newly prepared compound L2. A catalyst formed in situ from palladium(II) acetate and L1 efficiently mediated cyanation of aryl bromides bearing electron-donating substituents but failed in the analogous reactions with electron-poor substrates." @default.
- W3142959746 created "2021-04-13" @default.
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- W3142959746 date "2016-01-01" @default.
- W3142959746 modified "2023-09-23" @default.
- W3142959746 title "Different Performance of Two Isomeric Phosphinobiphenyl Amidosulfonates in Pd-Catalyzed Cyanation of Aryl Bromides" @default.
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