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- W3143588145 abstract "o-Carboryne undergoes at room temperature an efficient ene reaction with a large variety of alkynes and alkenes possessing an α-CH proton to give a series of o-carboranyl allenes and alkenes in good to high isolated yields. This reaction has a broad substrate scope from alkyl and aryl to silyl substituents. This protocol provides a facile synthetic method for accessing cage C-substituted carboranyl allenes and alkenes, which may be utilized as useful starting materials to synthesize multifunctionalized carboranes." @default.
- W3143588145 created "2021-04-13" @default.
- W3143588145 creator A5073501391 @default.
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- W3143588145 date "2021-04-02" @default.
- W3143588145 modified "2023-10-13" @default.
- W3143588145 title "Ene Reaction of <i>o</i>-Carboryne with Alkynes and Alkenes at Room Temperature: Synthesis of <i>o</i>-Carboranyl Allenes and Alkenes" @default.
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- W3143588145 doi "https://doi.org/10.1021/acs.orglett.1c00649" @default.
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