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• W3144083079 startingPage "1109" @default.
• W3144083079 abstract "The objective of this work was to investigate the influences of Klason lignin as a filler on the thermal stability and properties of natural rubber composites. The modulus and tensile strength of stabilized vulcanizates were measured before and after thermo-oxidative aging. It was determined that lignin filled natural rubber had significantly enhanced thermo-oxidative aging and mechanical properties compared to those of controlled samples. The reinforcement effect of lignin increased stress with lignin loading but it decreased at 20 phr, suggesting that the reinforcement mechanism of lignin was via strain-induced crystallization. The composite samples with 10 phr filler loading had the highest mechanical properties as well as thermo-oxidative degradation resistance. Such a finding could be due to interactions between the Klason lignin filler and natural rubber matrix. Based on the findings in this work, the degradation temperature of Klason lignin occurred at 420 °C. The absorption peaks at wavenumbers 1192 and 1374 cm−1 indicated that C–O stretching vibrations of the syringyl and guaiacyl rings of hardwood lignin existed. It was also found that the Klason lignin–rubber composite containing 10 phr had the highest stress–strain, 100% modulus, and tensile strength, while lignin showed increasing aging resistance of the composite comparable with commercial antioxidant at 1.5 phr. It appears that Klason lignin from rubberwood could be used as a green antioxidant and alternative reinforcing filler and for high performance eco-friendly natural rubber biocomposites." @default.
• W3144083079 created "2021-04-13" @default.
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• W3144083079 date "2021-03-31" @default.
• W3144083079 modified "2023-09-26" @default.
• W3144083079 title "The Characteristics of Natural Rubber Composites with Klason Lignin as a Green Reinforcing Filler: Thermal Stability, Mechanical and Dynamical Properties" @default.
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• W3144083079 doi "https://doi.org/10.3390/polym13071109" @default.
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